Synthesis, Crystal Structures, and DNA Binding Properties of Zinc(II) Complexes with 3-Pyridine Aldoxime
Joint Authors
Papi, Rigini
Raptopoulou, Catherine P.
Manessi-Zoupa, Evy
Katsoulakou, Eugenia
Konidaris, Konstantis F.
Kyriakidis, Dimitrios A.
Source
Bioinorganic Chemistry and Applications
Issue
Vol. 2010, Issue 2010 (31 Dec. 2010), pp.1-7, 7 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2010-11-02
Country of Publication
Egypt
No. of Pages
7
Main Subjects
Abstract EN
The employment of 3-pyridine aldoxime, (3-py)CHNOH, in ZnII chemistry has afforded two novel compounds: [Zn(acac)2{(3-py)CHNOH}]⋅H2O (1⋅H2O) [where acac- is the pentane-2,4-dionato(-1) ion] and [Zn2(O2CMe)4{(3-py)CHNOH}2] (2).
Complex 1⋅H2O crystallizes in the monoclinic space group P21/n.
The ZnII ion is five-coordinated, surrounded by four oxygen atoms of two acac- moieties and by the pyridyl nitrogen atom of the (3-py)CHNOH ligand.
Molecules of 1 interact with the water lattice molecules forming a 2D hydrogen-bonding network.
Complex 2 crystallizes in the triclinic P-1 space group and displays a dinuclear paddle-wheel structure.
Each ZnII exhibits a perfect square pyramidal geometry, with four carboxylate oxygen atoms at the basal plane and the pyridyl nitrogen of one monodentate (3-py)CHNOH ligand at the apex.
DNA mobility shift assays were performed for the determination of the in vitro effect of both complexes on the integrity and the electrophoretic mobility of pDNA.
American Psychological Association (APA)
Konidaris, Konstantis F.& Papi, Rigini& Katsoulakou, Eugenia& Raptopoulou, Catherine P.& Kyriakidis, Dimitrios A.& Manessi-Zoupa, Evy. 2010. Synthesis, Crystal Structures, and DNA Binding Properties of Zinc(II) Complexes with 3-Pyridine Aldoxime. Bioinorganic Chemistry and Applications،Vol. 2010, no. 2010, pp.1-7.
https://search.emarefa.net/detail/BIM-499291
Modern Language Association (MLA)
Konidaris, Konstantis F.…[et al.]. Synthesis, Crystal Structures, and DNA Binding Properties of Zinc(II) Complexes with 3-Pyridine Aldoxime. Bioinorganic Chemistry and Applications No. 2010 (2010), pp.1-7.
https://search.emarefa.net/detail/BIM-499291
American Medical Association (AMA)
Konidaris, Konstantis F.& Papi, Rigini& Katsoulakou, Eugenia& Raptopoulou, Catherine P.& Kyriakidis, Dimitrios A.& Manessi-Zoupa, Evy. Synthesis, Crystal Structures, and DNA Binding Properties of Zinc(II) Complexes with 3-Pyridine Aldoxime. Bioinorganic Chemistry and Applications. 2010. Vol. 2010, no. 2010, pp.1-7.
https://search.emarefa.net/detail/BIM-499291
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-499291