Effect of Polyvinyl Alcohol on the Growth, Structure, Morphology, and Electrical Conductivity of Polypyrrole Nanoparticles Synthesized via Microemulsion Polymerization
Joint Authors
Singh, Rajiv Kumar
Krishna, Anurag
Kumar, Amit
Source
Issue
Vol. 2012, Issue 2012 (31 Dec. 2012), pp.1-6, 6 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2012-09-24
Country of Publication
Egypt
No. of Pages
6
Main Subjects
Abstract EN
Polypyrrole (PPy) nanoparticles were synthesized via microemulsion polymerization technique using sodium dodecyl sulfate as surfactant.
Polyvinyl alcohol (PVA) was added as soft template during polymerization to modify the structure and properties of PPy nanoparticles.
The synthesized materials namely, PVA-free and PVA added were characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), scanning electron microscopy (SEM), and DC electrical conductivity measurements.
The sample synthesized in the presence of PVA has longer conjugation length as estimated from FT-IR investigation.
Temperature dependence (4.2–300 K) of DC electrical conductivity measurement reveals that the PVA has a strong effect on the polymerization mechanism of PPy giving evidence of H-bonded assistance during polymerization leading to the synthesis of better ordered polymer.
A growth mechanism has been proposed which explains the H-bonded assistance of PPy polymerization leading to enhanced structural ordering.
American Psychological Association (APA)
Krishna, Anurag& Kumar, Amit& Singh, Rajiv Kumar. 2012. Effect of Polyvinyl Alcohol on the Growth, Structure, Morphology, and Electrical Conductivity of Polypyrrole Nanoparticles Synthesized via Microemulsion Polymerization. ISRN Nanomaterials،Vol. 2012, no. 2012, pp.1-6.
https://search.emarefa.net/detail/BIM-499782
Modern Language Association (MLA)
Krishna, Anurag…[et al.]. Effect of Polyvinyl Alcohol on the Growth, Structure, Morphology, and Electrical Conductivity of Polypyrrole Nanoparticles Synthesized via Microemulsion Polymerization. ISRN Nanomaterials No. 2012 (2012), pp.1-6.
https://search.emarefa.net/detail/BIM-499782
American Medical Association (AMA)
Krishna, Anurag& Kumar, Amit& Singh, Rajiv Kumar. Effect of Polyvinyl Alcohol on the Growth, Structure, Morphology, and Electrical Conductivity of Polypyrrole Nanoparticles Synthesized via Microemulsion Polymerization. ISRN Nanomaterials. 2012. Vol. 2012, no. 2012, pp.1-6.
https://search.emarefa.net/detail/BIM-499782
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-499782