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Electrochemical Study of Esculetin Nitration by Digital Simulation of Cyclic Voltammograms
Joint Authors
Khalafi, Lida
Yari, Mohammad
Yadaei, Farzaneh
Majidzade, Shabnam
Source
Issue
Vol. 2013, Issue 2013 (31 Dec. 2013), pp.1-5, 5 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2012-07-01
Country of Publication
Egypt
No. of Pages
5
Main Subjects
Abstract EN
The reaction of electrochemically generated o-quinones from oxidation of esculetin as Michael acceptor with nitrite ion as nucleophile has been studied using cyclic voltammetry.
The reaction mechanism is believed to be EC, including oxidation of catechol moiety of esculetin followed by Michael addition of nitrite ion.
The observed homogeneous rate constants (kobs) for reactions were estimated by comparing the experimental voltammetric responses with the digitally simulated results based on the proposed mechanism.
Also the effects of pH and nucleophile concentration on voltammetric behavior and the rate constants of chemical reactions were described.
American Psychological Association (APA)
Khalafi, Lida& Yari, Mohammad& Yadaei, Farzaneh& Majidzade, Shabnam. 2012. Electrochemical Study of Esculetin Nitration by Digital Simulation of Cyclic Voltammograms. Journal of Chemistry،Vol. 2013, no. 2013, pp.1-5.
https://search.emarefa.net/detail/BIM-500983
Modern Language Association (MLA)
Khalafi, Lida…[et al.]. Electrochemical Study of Esculetin Nitration by Digital Simulation of Cyclic Voltammograms. Journal of Chemistry No. 2013 (2013), pp.1-5.
https://search.emarefa.net/detail/BIM-500983
American Medical Association (AMA)
Khalafi, Lida& Yari, Mohammad& Yadaei, Farzaneh& Majidzade, Shabnam. Electrochemical Study of Esculetin Nitration by Digital Simulation of Cyclic Voltammograms. Journal of Chemistry. 2012. Vol. 2013, no. 2013, pp.1-5.
https://search.emarefa.net/detail/BIM-500983
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-500983