Enhancement of Photocatalytic Activity on TiO2-Nitrogen-Doped Carbon Nanotubes Nanocomposites

Abstract EN

TiO2-nitrogen-doped carbon nanotubes (TiO2-CNx) nanocomposites are successfully synthesized via a facile hydrothermal method.

The prepared photocatalysts were systematically characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and thermogravimetric and differential scanning calorimetry analyses (TGA-DSC).

The results show that the TiO2 nanoparticles with a narrow size of 7 nm are uniformly deposited on CNx.

The photocatalytic activity of the nanocomposite was studied using methyl orange (MO) as a model organic pollutant.

The experimental results revealed that the strong linkage between the CNx and TiO2 played a significant role in improving photocatalytic activity.

However, the mechanical process for CNx and TiO2 mixtures showed lower activity than neat TiO2.

Moreover, TiO2-CNx nanocomposites exhibit much higher photocatalytic activity than that of neat TiO2 and TiO2-CNTs nanocomposites.

The improved photodegradation performances are attributed to the suppressed recombination of electrons and holes caused by the effective transfer of photogenerated electrons from TiO2 to CNx.