Laser Writing of Multiscale Chiral Polymer Metamaterials

Abstract EN

A new approach to metamaterials is presented that involves laser-based patterning of novel chiral polymer media, wherein chirality is realized at two distinct length scales, intrinsically at the molecular level and geometrically at a length scale on the order of the wavelength of the incident field.

In this approach, femtosecond-pulsed laser-induced two-photon lithography (TPL) is used to pattern a photoresist-chiral polymer mixture into planar chiral shapes.

Enhanced bulk chirality can be realized by tuning the wavelength-dependent chiral response at both the molecular and geometric level to ensure an overlap of their respective spectra.

The approach is demonstrated via the fabrication of a metamaterial consisting of a two-dimensional array of chiral polymer-based L-structures.

The fabrication process is described and modeling is performed to demonstrate the distinction between molecular and planar geometric-based chirality and the effects of the enhanced multiscale chirality on the optical response of such media.

This new approach to metamaterials holds promise for the development of tunable, polymer-based optical metamaterials with low loss.