The Catalytic Function of Nonheme Iron (III) Complex for Hydrocarbon Oxidation
Joint Authors
Source
Bioinorganic Chemistry and Applications
Issue
Vol. 2010, Issue 2010 (31 Dec. 2010), pp.1-9, 9 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2010-06-24
Country of Publication
Egypt
No. of Pages
9
Main Subjects
Abstract EN
A detailed catalytic study of LFeIIICl (where L=3-{2-[2-(3-hydroxy-1,3-diphenyl-allylideneamino)-ethylamino]-ethylimino}-1,3-diphenyl-propen-1-ol) for hydrocarbon oxidation was carried out, focusing on the role of solvent, atmospheric dioxygen, and oxidant on catalytic efficiency.
The data showed that LFeIIICl catalyst was efficient in homogeneous hydrocarbon oxidations providing significant yields.
Moreover, tert-BuOOH provided comparable oxidation yields with H2O2, slightly favoring the formation of alcohols and ketones versus epoxides.
Dioxygen intervened in the catalytic reaction, influencing the nature of oxidation products.
The polarity of solvent strongly influenced the reaction rates and the nature of oxidation products.
A mechanistic model is postulated assuming that LFeIIICl functions via the formation of iron-hydroperoxo-species, followed by a radical-based mechanistic path.
American Psychological Association (APA)
Bilis, Giorgos& Louloudi, Maria. 2010. The Catalytic Function of Nonheme Iron (III) Complex for Hydrocarbon Oxidation. Bioinorganic Chemistry and Applications،Vol. 2010, no. 2010, pp.1-9.
https://search.emarefa.net/detail/BIM-504229
Modern Language Association (MLA)
Bilis, Giorgos& Louloudi, Maria. The Catalytic Function of Nonheme Iron (III) Complex for Hydrocarbon Oxidation. Bioinorganic Chemistry and Applications No. 2010 (2010), pp.1-9.
https://search.emarefa.net/detail/BIM-504229
American Medical Association (AMA)
Bilis, Giorgos& Louloudi, Maria. The Catalytic Function of Nonheme Iron (III) Complex for Hydrocarbon Oxidation. Bioinorganic Chemistry and Applications. 2010. Vol. 2010, no. 2010, pp.1-9.
https://search.emarefa.net/detail/BIM-504229
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-504229