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Diesters Biolubricant Base Oil : Synthesis, Optimization, Characterization, and Physicochemical Characteristics
Joint Authors
Abdullah, Bashar Mudhaffar
Salimon, Jumat
Salih, Nadia
Source
International Journal of Chemical Engineering
Issue
Vol. 2012, Issue 2012 (31 Dec. 2012), pp.1-10, 10 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2012-02-15
Country of Publication
Egypt
No. of Pages
10
Main Subjects
Engineering Sciences and Information Technology
Abstract EN
Diesters biolubricant base oil, oleyl 9(12)-hydroxy-10(13)-oleioxy-12(9)-octadecanoate (OLHYOOD) was synthesized based on the esterification reaction of 9,12-hydroxy-10,13-oleioxy-12-octadecanoic acid (HYOOA) with oleyl alcohol (OL) and catalyzed by sulfuric acid (SA).
Optimum conditions of the experiment to obtain high yield % of OLHYOOD were predicted at ratio of OL/HYOOA of 2 : 1 mol/mol, ratio of SA/HYOOA of 0.7 : 1 mol/mol, reaction temperature 110°C, and 7 h of reaction time.
At this condition, the yield of OLHYOOD was 88.7%.
Disappearance of carboxylic acid (C=O) peak has been observed by FTIR with appearance of ester (C=O) peak at 1738 cm-1.
13C, and 1H NMR spectra analyses confirmed the result of OLHYOOD with the appearance of carbon-ester (C=O) chemical shift at 173.93 ppm and at 4.05 ppm for 13C and 1H NMR, respectively.
The physicochemical characteristics of the OLHYOOD were also determined, which showed improved low temperature properties (PP) −62°C, viscosity index (VI) at 192 and also increased oxidative stability (OT) up to 215.24°C.
American Psychological Association (APA)
Salimon, Jumat& Salih, Nadia& Abdullah, Bashar Mudhaffar. 2012. Diesters Biolubricant Base Oil : Synthesis, Optimization, Characterization, and Physicochemical Characteristics. International Journal of Chemical Engineering،Vol. 2012, no. 2012, pp.1-10.
https://search.emarefa.net/detail/BIM-506299
Modern Language Association (MLA)
Salimon, Jumat…[et al.]. Diesters Biolubricant Base Oil : Synthesis, Optimization, Characterization, and Physicochemical Characteristics. International Journal of Chemical Engineering No. 2012 (2012), pp.1-10.
https://search.emarefa.net/detail/BIM-506299
American Medical Association (AMA)
Salimon, Jumat& Salih, Nadia& Abdullah, Bashar Mudhaffar. Diesters Biolubricant Base Oil : Synthesis, Optimization, Characterization, and Physicochemical Characteristics. International Journal of Chemical Engineering. 2012. Vol. 2012, no. 2012, pp.1-10.
https://search.emarefa.net/detail/BIM-506299
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-506299