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Synthesis, Spectroscopic, and Biological Studies on New Zirconium(IV) Porphyrins with Axial Ligand
Joint Authors
Bhagat, Madhulika
Katoch, Sapna
Anand, Sunil Kumar
Bajju, Gauri Devi
Kapahi, Ashu
Devi, Geeta
Kundan, Sujata
Gupta, Deepmala
Source
Bioinorganic Chemistry and Applications
Issue
Vol. 2013, Issue 2013 (31 Dec. 2013), pp.1-15, 15 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2013-09-10
Country of Publication
Egypt
No. of Pages
15
Main Subjects
Abstract EN
A series of parasubstituted tetraphenylporphyrin zirconium(IV) salicylate complexes (SA/5-SSAZr(IV)RTPP, R = p-H, p-CH3, p-NO2, p-Cl, SA = salicylate, and 5-SSA = 5-sulfosalicylate) have been synthesized, and the spectral properties of free base porphyrins, their corresponding metallated, and axially ligated zirconium(IV) porphyrin compounds were compared with each other.
A detailed analysis of ultraviolet-visible (UV-vis), proton nulcear magnetic resonance (1H NMR) spectroscopy, infrared (IR) spectroscopy, and elemental analysis suggested the transformation from free base porphyrins to zirconium(IV) porphyrins.
The ability of the metal in this complex for extra coordination of solvent molecules was confirmed by ESI-MS spectra.
Besides the fluorescence, cyclic voltammetry, and thermogravimetric studies, the complexes were also screened for antimicrobial and anticancer activities.
Among all the complexes, 5-SSAZr(p-NO2TPP) shows high antibacterial activity.
American Psychological Association (APA)
Bajju, Gauri Devi& Devi, Geeta& Katoch, Sapna& Bhagat, Madhulika& Gupta, Deepmala& Kapahi, Ashu…[et al.]. 2013. Synthesis, Spectroscopic, and Biological Studies on New Zirconium(IV) Porphyrins with Axial Ligand. Bioinorganic Chemistry and Applications،Vol. 2013, no. 2013, pp.1-15.
https://search.emarefa.net/detail/BIM-506742
Modern Language Association (MLA)
Bajju, Gauri Devi…[et al.]. Synthesis, Spectroscopic, and Biological Studies on New Zirconium(IV) Porphyrins with Axial Ligand. Bioinorganic Chemistry and Applications No. 2013 (2013), pp.1-15.
https://search.emarefa.net/detail/BIM-506742
American Medical Association (AMA)
Bajju, Gauri Devi& Devi, Geeta& Katoch, Sapna& Bhagat, Madhulika& Gupta, Deepmala& Kapahi, Ashu…[et al.]. Synthesis, Spectroscopic, and Biological Studies on New Zirconium(IV) Porphyrins with Axial Ligand. Bioinorganic Chemistry and Applications. 2013. Vol. 2013, no. 2013, pp.1-15.
https://search.emarefa.net/detail/BIM-506742
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-506742