In Search for Titanocene Complexes with Improved Cytotoxic Activity : Synthesis, X-Ray Structure, and Spectroscopic Study of Bis(η5-cyclopentadienyl)difluorotitanium(IV)
Joint Authors
Klouras, Nikolaos
Koleros, Elias
Raptopoulou, Catherine P.
Psycharis, Vassilis
Perlepes, Spyros P.
Stamatatos, Theocharis C.
Source
Bioinorganic Chemistry and Applications
Issue
Vol. 2010, Issue 2010 (31 Dec. 2010), pp.1-6, 6 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2010-06-23
Country of Publication
Egypt
No. of Pages
6
Main Subjects
Abstract EN
The 1 : 2 reaction of [Ti(η5-C5H5)2Cl2] and AgF in CHCl3/H2O yielded the fluoro analog [Ti(η5-C5H5)2F2] (1) in almost quantitative yield (C5H5 is the cyclopentadienyl group).
The coordination about the TiIV atom formed by two fluoro ligands and the centroids of the cyclopentadienyl rings is distorted tetrahedral.
The compound crystallizes in the orthorhombic space group C2cm.
The lattice constants are a=5.9055(4),b=10.3021(5),c=14.2619(9) Å, and α=β=γ=90°.
The complex has been characterized by elemental analyses and spectroscopic (IR, H1 NMR) data.
A structural comparison of the four members of the [Ti(η5-C5H5)2X2] family of complexes (X=F,Cl,Br,I) is attempted.
American Psychological Association (APA)
Koleros, Elias& Stamatatos, Theocharis C.& Psycharis, Vassilis& Raptopoulou, Catherine P.& Perlepes, Spyros P.& Klouras, Nikolaos. 2010. In Search for Titanocene Complexes with Improved Cytotoxic Activity : Synthesis, X-Ray Structure, and Spectroscopic Study of Bis(η5-cyclopentadienyl)difluorotitanium(IV). Bioinorganic Chemistry and Applications،Vol. 2010, no. 2010, pp.1-6.
https://search.emarefa.net/detail/BIM-507684
Modern Language Association (MLA)
Koleros, Elias…[et al.]. In Search for Titanocene Complexes with Improved Cytotoxic Activity : Synthesis, X-Ray Structure, and Spectroscopic Study of Bis(η5-cyclopentadienyl)difluorotitanium(IV). Bioinorganic Chemistry and Applications No. 2010 (2010), pp.1-6.
https://search.emarefa.net/detail/BIM-507684
American Medical Association (AMA)
Koleros, Elias& Stamatatos, Theocharis C.& Psycharis, Vassilis& Raptopoulou, Catherine P.& Perlepes, Spyros P.& Klouras, Nikolaos. In Search for Titanocene Complexes with Improved Cytotoxic Activity : Synthesis, X-Ray Structure, and Spectroscopic Study of Bis(η5-cyclopentadienyl)difluorotitanium(IV). Bioinorganic Chemistry and Applications. 2010. Vol. 2010, no. 2010, pp.1-6.
https://search.emarefa.net/detail/BIM-507684
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-507684
