Theoretical Evaluation of Ultrasonic Velocities in Binary Liquid Mixtures of Anisaldehyde with Some Alcoxyethanols at Different Temperatures

Abstract EN

Ultrasonic velocities and densities of the binary liquid mixtures of anisaldehyde with alcoxyethanols like methoxyethanol (MOE), ethoxyethanol (EOE), and butoxyethanol (BOE) have been measured at temperatures 303.15 K, 308.15 K, 313.15 K, and 318.15 K over the entire composition range of mole fractions.

The theoretical values of ultrasonic velocity were evaluated using Nomoto's relation (UNR), impedance relation (UIR), ideal mixing relation (UIMR), Jungie's relation (UJR), and Rao’s specific velocity relation (UR).

The molecular interaction parameter (χ) has been evaluated from the values of experimental and theoretical velocities.

The variation of this interaction parameter with the composition mixture has been discussed in terms of molecular interactions.