Mononuclear and Dinuclear Manganese(II) Complexes from the Use of Methyl(2-pyridyl)ketone Oxime
Joint Authors
Tasiopoulos, Anastasios J.
Raptopoulou, Catherine P.
Efthymiou, Constantinos G.
Nastopoulos, Vassilios
Papatriantafyllopoulou, Constantina
Perlepes, Spyros P.
Source
Bioinorganic Chemistry and Applications
Issue
Vol. 2010, Issue 2010 (31 Dec. 2010), pp.1-9, 9 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2010-07-04
Country of Publication
Egypt
No. of Pages
9
Main Subjects
Abstract EN
The reactions of methyl(2-pyridyl)ketone oxime, (py)C(Me)NOH, with manganese(II) sulfate monohydrate have been investigated.
The reaction between equimolar quantities of MnSO4⋅H2O and (py)C(Me)NOH in H2O lead to the dinuclear complex [Mn2(SO4)2{(py)C(Me)NOH}4]⋅(py)C(Me)NOH, 1⋅(py)C(Me)NOH, while employment of NaOMe as base affords the compound [Mn(HCO2)2{(py)C(Me)NOH}2] (2).
The structures of both compounds have been determined by single crystal X-ray diffraction.
In both complexes, the organic ligand chelates through its nitrogen atoms.
The IR data are discussed in terms of the nature of bonding and the structures of the two complexes.
American Psychological Association (APA)
Efthymiou, Constantinos G.& Nastopoulos, Vassilios& Raptopoulou, Catherine P.& Tasiopoulos, Anastasios J.& Perlepes, Spyros P.& Papatriantafyllopoulou, Constantina. 2010. Mononuclear and Dinuclear Manganese(II) Complexes from the Use of Methyl(2-pyridyl)ketone Oxime. Bioinorganic Chemistry and Applications،Vol. 2010, no. 2010, pp.1-9.
https://search.emarefa.net/detail/BIM-511606
Modern Language Association (MLA)
Efthymiou, Constantinos G.…[et al.]. Mononuclear and Dinuclear Manganese(II) Complexes from the Use of Methyl(2-pyridyl)ketone Oxime. Bioinorganic Chemistry and Applications No. 2010 (2010), pp.1-9.
https://search.emarefa.net/detail/BIM-511606
American Medical Association (AMA)
Efthymiou, Constantinos G.& Nastopoulos, Vassilios& Raptopoulou, Catherine P.& Tasiopoulos, Anastasios J.& Perlepes, Spyros P.& Papatriantafyllopoulou, Constantina. Mononuclear and Dinuclear Manganese(II) Complexes from the Use of Methyl(2-pyridyl)ketone Oxime. Bioinorganic Chemistry and Applications. 2010. Vol. 2010, no. 2010, pp.1-9.
https://search.emarefa.net/detail/BIM-511606
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-511606
