Synchrotron-Radiation X-Ray Investigation of Li+Na+ Intercalation into Prussian Blue Analogues
Joint Authors
Takachi, Masamitsu
Matsuda, Tomoyuki
Kurihara, Yutaro
Moritomo, Yutaka
Source
Advances in Materials Science and Engineering
Issue
Vol. 2013, Issue 2013 (31 Dec. 2013), pp.1-17, 17 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2013-10-08
Country of Publication
Egypt
No. of Pages
17
Main Subjects
Engineering Sciences and Information Technology
Abstract EN
Prussian blue analogies (PBAs) are promising cathode materials for lithium ion (LIB) and sodium ion (SIB) secondary batteries, reflecting their covalent and nanoporous host structure.
With use of synchrotron-radiation (SR) X-ray source, we investigated the structural and electronic responses of the host framework of PBAs against Li+ and Na+ intercalation by means of the X-ray powder diffraction (XRD) and X-ray absorption spectroscopy (XAS).
The structural investigation reveals a robust nature of the host framework against Li+ and Na+ intercalation, which is advantageous for the stability and lifetime of the batteries.
The spectroscopic investigation identifies the redox processes in respective plateaus in the discharge curves.
We further compare these characteristics with those of the conventional cathode materials, such as, LiCoO2, LiFePO4, and LiMn2O4.
American Psychological Association (APA)
Moritomo, Yutaka& Takachi, Masamitsu& Kurihara, Yutaro& Matsuda, Tomoyuki. 2013. Synchrotron-Radiation X-Ray Investigation of Li+Na+ Intercalation into Prussian Blue Analogues. Advances in Materials Science and Engineering،Vol. 2013, no. 2013, pp.1-17.
https://search.emarefa.net/detail/BIM-512116
Modern Language Association (MLA)
Moritomo, Yutaka…[et al.]. Synchrotron-Radiation X-Ray Investigation of Li+Na+ Intercalation into Prussian Blue Analogues. Advances in Materials Science and Engineering No. 2013 (2013), pp.1-17.
https://search.emarefa.net/detail/BIM-512116
American Medical Association (AMA)
Moritomo, Yutaka& Takachi, Masamitsu& Kurihara, Yutaro& Matsuda, Tomoyuki. Synchrotron-Radiation X-Ray Investigation of Li+Na+ Intercalation into Prussian Blue Analogues. Advances in Materials Science and Engineering. 2013. Vol. 2013, no. 2013, pp.1-17.
https://search.emarefa.net/detail/BIM-512116
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-512116