Synchrotron-Radiation X-Ray Investigation of Li+Na+ Intercalation into Prussian Blue Analogues

Joint Authors

Takachi, Masamitsu
Matsuda, Tomoyuki
Kurihara, Yutaro
Moritomo, Yutaka

Source

Advances in Materials Science and Engineering

Issue

Vol. 2013, Issue 2013 (31 Dec. 2013), pp.1-17, 17 p.

Publisher

Hindawi Publishing Corporation

Publication Date

2013-10-08

Country of Publication

Egypt

No. of Pages

17

Main Subjects

Engineering Sciences and Information Technology

Abstract EN

Prussian blue analogies (PBAs) are promising cathode materials for lithium ion (LIB) and sodium ion (SIB) secondary batteries, reflecting their covalent and nanoporous host structure.

With use of synchrotron-radiation (SR) X-ray source, we investigated the structural and electronic responses of the host framework of PBAs against Li+ and Na+ intercalation by means of the X-ray powder diffraction (XRD) and X-ray absorption spectroscopy (XAS).

The structural investigation reveals a robust nature of the host framework against Li+ and Na+ intercalation, which is advantageous for the stability and lifetime of the batteries.

The spectroscopic investigation identifies the redox processes in respective plateaus in the discharge curves.

We further compare these characteristics with those of the conventional cathode materials, such as, LiCoO2, LiFePO4, and LiMn2O4.

American Psychological Association (APA)

Moritomo, Yutaka& Takachi, Masamitsu& Kurihara, Yutaro& Matsuda, Tomoyuki. 2013. Synchrotron-Radiation X-Ray Investigation of Li+Na+ Intercalation into Prussian Blue Analogues. Advances in Materials Science and Engineering،Vol. 2013, no. 2013, pp.1-17.
https://search.emarefa.net/detail/BIM-512116

Modern Language Association (MLA)

Moritomo, Yutaka…[et al.]. Synchrotron-Radiation X-Ray Investigation of Li+Na+ Intercalation into Prussian Blue Analogues. Advances in Materials Science and Engineering No. 2013 (2013), pp.1-17.
https://search.emarefa.net/detail/BIM-512116

American Medical Association (AMA)

Moritomo, Yutaka& Takachi, Masamitsu& Kurihara, Yutaro& Matsuda, Tomoyuki. Synchrotron-Radiation X-Ray Investigation of Li+Na+ Intercalation into Prussian Blue Analogues. Advances in Materials Science and Engineering. 2013. Vol. 2013, no. 2013, pp.1-17.
https://search.emarefa.net/detail/BIM-512116

Data Type

Journal Articles

Language

English

Notes

Includes bibliographical references

Record ID

BIM-512116