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Chiral Solid Solutions for the NMR Analysis of Enantiomers : A Potential New Approach to Chiral Analysis
Author
Source
Issue
Vol. 2013, Issue 2013 (31 Dec. 2013), pp.1-6, 6 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2012-09-06
Country of Publication
Egypt
No. of Pages
6
Main Subjects
Abstract EN
Differences between the solid-state 13C CP-MAS NMR spectra of holemic samples of the two enantiomers of 2,2′-dihydroxy-1,1′-binaphthyl (binol) were not sufficiently emphatic to reliably distinguish them, though they are readily distinguishable from the spectrum of the bimate of the compound crystallized from an equimatic sample.
Inducing an additional chiral environment by cocondensation with sucrose as a chiral selector (CS) provided a method to yield differential spectra for the two enantiomers and thus effect enantiodifferentiation by way of solid-state NMR using weak interactions from a CS.
American Psychological Association (APA)
Klika, Karel D.. 2012. Chiral Solid Solutions for the NMR Analysis of Enantiomers : A Potential New Approach to Chiral Analysis. Journal of Spectroscopy،Vol. 2013, no. 2013, pp.1-6.
https://search.emarefa.net/detail/BIM-512374
Modern Language Association (MLA)
Klika, Karel D.. Chiral Solid Solutions for the NMR Analysis of Enantiomers : A Potential New Approach to Chiral Analysis. Journal of Spectroscopy No. 2013 (2013), pp.1-6.
https://search.emarefa.net/detail/BIM-512374
American Medical Association (AMA)
Klika, Karel D.. Chiral Solid Solutions for the NMR Analysis of Enantiomers : A Potential New Approach to Chiral Analysis. Journal of Spectroscopy. 2012. Vol. 2013, no. 2013, pp.1-6.
https://search.emarefa.net/detail/BIM-512374
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-512374