Synthesis, characterization and single crystal X-rayanalysis of chlorobis (N,N-dimethyldithiocarbamato- S,S1) antimony (III)
Joint Authors
Chauhan, H. P. S.
Carpenter, Jaswant
Source
Journal of Saudi Chemical Society
Issue
Vol. 19, Issue 4 (31 Jul. 2015), pp.417-422, 6 p.
Publisher
Publication Date
2015-07-31
Country of Publication
Saudi Arabia
No. of Pages
6
Main Subjects
Topics
Abstract EN
The title compound chlorobis(N,N-dimethyldithiocarbamato-S,S0)antimony(III) has been prepared in distilled acetonitrile and characterized by physicochemical [melting point and molecular weight determination, elemental analysis (C, H, N, S & Sb)], spectral [FT–IR, far IR, NMR (1H & 13C)] studies.
The crystal and molecular structure was further confirmed using single crystal X-ray diffraction analysis which features a five-coordinate geometry for antimony(III) within a ClS4 donor set.
The distortion in the co-planarity of ClSbS3 evidences the stereochemical influence exerts by the lone pair of electrons on antimony(III).
Two centrosymmetrically related molecule held together via C–HÆÆÆCl secondary interaction result in molecular aggregation of the compound.
American Psychological Association (APA)
Chauhan, H. P. S.& Carpenter, Jaswant. 2015. Synthesis, characterization and single crystal X-rayanalysis of chlorobis (N,N-dimethyldithiocarbamato- S,S1) antimony (III). Journal of Saudi Chemical Society،Vol. 19, no. 4, pp.417-422.
https://search.emarefa.net/detail/BIM-590420
Modern Language Association (MLA)
Chauhan, H. P. S.& Carpenter, Jaswant. Synthesis, characterization and single crystal X-rayanalysis of chlorobis (N,N-dimethyldithiocarbamato- S,S1) antimony (III). Journal of Saudi Chemical Society Vol. 19, no. 4 (Jul. 2015), pp.417-422.
https://search.emarefa.net/detail/BIM-590420
American Medical Association (AMA)
Chauhan, H. P. S.& Carpenter, Jaswant. Synthesis, characterization and single crystal X-rayanalysis of chlorobis (N,N-dimethyldithiocarbamato- S,S1) antimony (III). Journal of Saudi Chemical Society. 2015. Vol. 19, no. 4, pp.417-422.
https://search.emarefa.net/detail/BIM-590420
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 421-422
Record ID
BIM-590420