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Charge transport at liquid liquid interface
Other Title(s)
انتقال الشحنة لسطح سائل سائل
Joint Authors
al-Ukayli, Hadi Jabbar Majbal
al-Sadi, Adil Ali Mansur
Source
Ibn al-Haitham Journal for Pure and Applied Science
Issue
Vol. 26, Issue 3 (31 Dec. 2013), pp.94-103, 10 p.
Publisher
University of Baghdad College of Education for Pure Science / Ibn al-Haitham
Publication Date
2013-12-31
Country of Publication
Iraq
No. of Pages
10
Main Subjects
Abstract EN
Charge transfer (CT) at liquid/liquid inte^aces are described theoretically depending on the quantum theory .A model that derived used to calculate the rate constant of transport at liquid/liquid inte^aces.
The calculation of the rate constant of charge transfer depends on the calculation of the reorganization energy, driving force ,and the coupling coefficient .
Large reorganization energies and large rate constant for charge transfer ,indicate that the transitions involve more energy to happen .
The system have large E0 (ieV) refers that type of liquid is more reactive media than other liquid types with same donor.
Driving force energy to drive the charge increases with the increase of absorption energy and decrease of in wave length.
Height barrier at liquid/liquid interface that decreasing with decreasing the driving force energy and increasing the absorption energies .Charge transfer is so much small as a barrier of large values but in the low values of barrier ,the transfer is most probable.
The large height barrier exclusion transfers across liquid/liquid system and the charger suffers from much resistant to transfer .
However, this excluded transfer could be significantly large for high barrier and small concentrations .The theoretical values of rate constant of charge transfer show a good agreement with some of the experimental studies.
American Psychological Association (APA)
al-Ukayli, Hadi Jabbar Majbal& al-Sadi, Adil Ali Mansur. 2013. Charge transport at liquid liquid interface. Ibn al-Haitham Journal for Pure and Applied Science،Vol. 26, no. 3, pp.94-103.
https://search.emarefa.net/detail/BIM-598788
Modern Language Association (MLA)
al-Ukayli, Hadi Jabbar Majbal& al-Sadi, Adil Ali Mansur. Charge transport at liquid liquid interface. Ibn al-Haitham Journal for Pure and Applied Science Vol. 26, no. 3 (Dec. 2013), pp.94-103.
https://search.emarefa.net/detail/BIM-598788
American Medical Association (AMA)
al-Ukayli, Hadi Jabbar Majbal& al-Sadi, Adil Ali Mansur. Charge transport at liquid liquid interface. Ibn al-Haitham Journal for Pure and Applied Science. 2013. Vol. 26, no. 3, pp.94-103.
https://search.emarefa.net/detail/BIM-598788
Data Type
Journal Articles
Language
English
Notes
Includes appendix : p. 99-102
Record ID
BIM-598788