Syntheses, characterization and biological activity of a new ligand [N-(5 sulfanyl-1, 3, 4-thiadiazol-2-yl) acetamide with some transition metal complexes
Other Title(s)
تحضير و تشخيص و دراسة الفعالية البايولوجية لليكاند مع بعض معقدات العناصر الانتقالية [N-(5-sulfanyl-1, 3, 4-thiadiazol-2-yl)acetamide
Joint Authors
Salman, Wiam Abd al-Khidr
Fulayfil, Ibrahim Abbud
al-Dukhaily, Muhsin E.
Source
Issue
Vol. 4, Issue 3 (30 Jun. 2014), pp.130-136, 7 p.
Publisher
University of Thi-Qar College of Science
Publication Date
2014-06-30
Country of Publication
Iraq
No. of Pages
7
Main Subjects
Abstract EN
A-new series of transition metal (Cr(III),Fe(III), Co(II) , Ni(II)and Cu(II) ) complexes of ligand [N-(5-sulfonyl-1, 3, 4,thiadiazol-2-yl)acetamide were synthesized.
All the synthesized complexes were characterized by analytical techniques, magnetic susceptibility measurements, elemental analyses, conductance, IR , 1HNMR and mass spectra.
The electrolytic behavior were confirmed from their conductance data .
It may be concluded that the ligand coordinate through Nitrogen and sulfur atoms as shown in figure (6).
for all complexes.
The ligand acts as a didentate ligand coordinating through the sulfur[S6] and the nitrogen atom of shiff base [N5].
This view is further supported by the appearance of a band corresponding to the metal–nitrogen stretching vibration at( 547-563) cm–1 in the complexes.
From results it was suggested tetrahedral geometry for Ni(II) and Cu(II) complexes, while Cr(III),Fe(III) and Co (III)complexes were assigned octahedral geometrics.
All complexes and their parent organic moiety have been screened for antibacterial by using spread method and measurement inhibition zone by
American Psychological Association (APA)
Salman, Wiam Abd al-Khidr& Fulayfil, Ibrahim Abbud& al-Dukhaily, Muhsin E.. 2014. Syntheses, characterization and biological activity of a new ligand [N-(5 sulfanyl-1, 3, 4-thiadiazol-2-yl) acetamide with some transition metal complexes. Journal of Thi-Qar Science،Vol. 4, no. 3, pp.130-136.
https://search.emarefa.net/detail/BIM-599871
Modern Language Association (MLA)
Salman, Wiam Abd al-Khidr…[et al.]. Syntheses, characterization and biological activity of a new ligand [N-(5 sulfanyl-1, 3, 4-thiadiazol-2-yl) acetamide with some transition metal complexes. Journal of Thi-Qar Science Vol. 4, no. 3 (Jun. 2014), pp.130-136.
https://search.emarefa.net/detail/BIM-599871
American Medical Association (AMA)
Salman, Wiam Abd al-Khidr& Fulayfil, Ibrahim Abbud& al-Dukhaily, Muhsin E.. Syntheses, characterization and biological activity of a new ligand [N-(5 sulfanyl-1, 3, 4-thiadiazol-2-yl) acetamide with some transition metal complexes. Journal of Thi-Qar Science. 2014. Vol. 4, no. 3, pp.130-136.
https://search.emarefa.net/detail/BIM-599871
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 136
Record ID
BIM-599871