Perturbation effect of solvent on the photo-physical processes of fluorescence solute at low temperature

Dissertant

al-Rawi, Asma Naji Ahmad

Thesis advisor

al-Wattar, Abbas Jasim Hammadi
al-Maliki, Firas Jawad K.

Comitee Members

Sadiq, Zaynab S.
Hadi, Mahasin Fadil
Hamid, Muhammad A.

University

University of Baghdad

Faculty

College of Science

Department

Department of Physics

University Country

Iraq

Degree

Master

Degree Date

2014

English Abstract

In the present work, the low temperature spectroscopy of Anthracene and Benzoanthracene molecules in different solvents has been studied at a fixed molar concentration.

The temperature range has been taken from room temperature down to liquid nitrogen temperature (77K).

Polar and nonpolar solvents; Ethanol, Isopropanol, Hexane, Heptane and Nonane, have been used in order to study the environment effect on the absorption and fluorescence spectra of these molecules.

On the other hand, some of the spectroscopic parameters have been determined as functions of solvent polarity and temperature.

Thus, the fluorescence lifetime has been measured using the Photon Technology International (PTI) instrument.

The results indicate that the band width at full half maximum (FWHM) increases, while the peak emission cross section (σp) decreases, with increasing of solvent polarity and temperature.

The Shpol'skii spectra of these molecules show clearly enhancement, in which sharp and highly- resolved fine structure spectra have been observed at 77K.

Main Subjects

Physics

No. of Pages

88

Table of Contents

Table of contents.

Abstract.

Chapter One : Introduction and basic concepts.

Chapter Two : Experimental part.

Chapter Three : Results and discussion.

References.

American Psychological Association (APA)

al-Rawi, Asma Naji Ahmad. (2014). Perturbation effect of solvent on the photo-physical processes of fluorescence solute at low temperature. (Master's theses Theses and Dissertations Master). University of Baghdad, Iraq
https://search.emarefa.net/detail/BIM-607235

Modern Language Association (MLA)

al-Rawi, Asma Naji Ahmad. Perturbation effect of solvent on the photo-physical processes of fluorescence solute at low temperature. (Master's theses Theses and Dissertations Master). University of Baghdad. (2014).
https://search.emarefa.net/detail/BIM-607235

American Medical Association (AMA)

al-Rawi, Asma Naji Ahmad. (2014). Perturbation effect of solvent on the photo-physical processes of fluorescence solute at low temperature. (Master's theses Theses and Dissertations Master). University of Baghdad, Iraq
https://search.emarefa.net/detail/BIM-607235

Language

English

Data Type

Arab Theses

Record ID

BIM-607235