Synthesis of new bismuth (III) compound and adducts of benzothiazol disulfide derivatives and their complexes with Co (II), Ni (II) and Cu (II)
Joint Authors
Source
al-Tarbiyah wa-al-Ilm : Majallat ilmiyah lil-Buhuth al-Ilmiyah al-Asasiyah
Issue
Vol. 22, Issue 2 (30 Jun. 2009), pp.1-8, 8 p.
Publisher
University of Mosul College of Education for Pure Science
Publication Date
2009-06-30
Country of Publication
Iraq
No. of Pages
8
Main Subjects
Abstract AR
يتفاعل فمز البزموث مع ثنائي بنزوثاي ازول ثنائي الكبريتيد C7H4NS 22 في التولوين ليعطي المركب Bi(S2C7H4N)3 خلال تفاعل الأكسدة المضافة و بصورة مشابهة فان مزيج البزموث و C7H4NS2)2) و اليود و بنسبة مولية 1:1:0.5 في التولوين يؤدي إلى تكوين المركب Bi(S2C7H4N)2I .
تم تحضير مركبات الإضافة لمركبات البزموث الجديدة مع ثلاثي فنيل فوسفين و 1،10-فينانثرولين من خلال تفاعل الإضافة المباشرة بين مركبات البزموث و الليكاندات أعاله.
المعقدات ثلاثية النوى ذوات الصيغة العامة[Bi(S2C7H4N)3(MCl2)2] تم تحضيرها من خلال التفاعل لا مباشر ما بين NiCl2.6H2O،CoCl2.6H2O أو CuCl2.4H2O مع مركبات البزموث مركبات البزموث و مركبات الإضافة و المعقدات تم تشخيصها بالطرق الفيزياوية و الكيمياوية و بالطرق الطيفية.
Abstract EN
Bismuth metal react with dibenzothiazole disulfide (C7H4NS2)2 in refluxing toluene to give the compound Bi(S2C7H4N)3 through oxidative addition reaction, similary, a mixture of bismuth, (C7H4NS2)2 and iodine in 1:1:0.5 molar ratio in refluxing toluene lead to the formation of Bi(S2C7H4N)2I.
Adducts of new bismuth compounds with triphenyl-phosphine and 1,10-phenanthroline have been synthesized by direct reaction between the bismuth compounds and the neutral ligand.
Trinuclear complexes of the general formula[Bi(S2C7H4N)3(MCl2)2] were prepared by a direct reaction of CoCl2.6H2O, NiCl2.6H2O or CuCl2.4H2O with bismuth compound.
The bismuth compounds their adducts and the complexes have been characterized physico-chemically and spectro-scopically.
American Psychological Association (APA)
Butrus, Nabil H.& Jasim, Z. U.. 2009. Synthesis of new bismuth (III) compound and adducts of benzothiazol disulfide derivatives and their complexes with Co (II), Ni (II) and Cu (II). al-Tarbiyah wa-al-Ilm : Majallat ilmiyah lil-Buhuth al-Ilmiyah al-Asasiyah،Vol. 22, no. 2, pp.1-8.
https://search.emarefa.net/detail/BIM-621817
Modern Language Association (MLA)
Butrus, Nabil H.& Jasim, Z. U.. Synthesis of new bismuth (III) compound and adducts of benzothiazol disulfide derivatives and their complexes with Co (II), Ni (II) and Cu (II). al-Tarbiyah wa-al-Ilm : Majallat ilmiyah lil-Buhuth al-Ilmiyah al-Asasiyah Vol. 22, no. 2 (Jun. 2009), pp.1-8.
https://search.emarefa.net/detail/BIM-621817
American Medical Association (AMA)
Butrus, Nabil H.& Jasim, Z. U.. Synthesis of new bismuth (III) compound and adducts of benzothiazol disulfide derivatives and their complexes with Co (II), Ni (II) and Cu (II). al-Tarbiyah wa-al-Ilm : Majallat ilmiyah lil-Buhuth al-Ilmiyah al-Asasiyah. 2009. Vol. 22, no. 2, pp.1-8.
https://search.emarefa.net/detail/BIM-621817
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 8
Record ID
BIM-621817
