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Synthesis and characterization of trihydro mono and dihydrobis (indole-3-acetic acid) borate ligands and some of their metal complexes
Other Title(s)
تحضير و تشخيص ليكاندات بورات ثلاثي هيدرو أحادي و ثنائي هيدرو ثنائي (اندول-3-حامض الخليك) و بعض معقداتها الفلزية
Author
Source
Issue
Vol. 56, Issue 4A (31 Dec. 2015), pp.2762-2772, 11 p.
Publisher
University of Baghdad College of Science
Publication Date
2015-12-31
Country of Publication
Iraq
No. of Pages
11
Main Subjects
Abstract EN
Two new ligands Na2[ H3B (BDIA)].0.05H2O (L1)(BDIA = 1-Boranyl-2,3- Dihydro-1H-Indol-3-yl)]Acetic Acid and Na3[H2B(BDIA)2].0.3H2O.0.3CH3Ph (L2) were synthesized by reaction of NaBH4 with indole -3- acetic acid (IAA) .
The coordination properties of ligands were studied with Co(II) , Ni(II) , Cu(II) and Pt(IV) ions.
Characterization and structural aspects of the prepared compounds were elucidated by 1HNMR, FTIR electronic spectra, magnetic susceptibility, elemental and metal analysis, thermal analysis (TG & DTG) and conductivity measurements.
The obtained data for metal complexes suggested square planar geometry for copper complexes, octahedral geometry for nickel and platinium complexes and tetrahedral geometry for cobalt complex.
The analytical data confirmed that the ligands were coordinated to the metals via oxygen atom of carboxylate groups and by agostic hydrogen of borate (B-H M agostic interaction).
American Psychological Association (APA)
Khalil, Asma Muhammad Nuri. 2015. Synthesis and characterization of trihydro mono and dihydrobis (indole-3-acetic acid) borate ligands and some of their metal complexes. Iraqi Journal of Science،Vol. 56, no. 4A, pp.2762-2772.
https://search.emarefa.net/detail/BIM-651474
Modern Language Association (MLA)
Khalil, Asma Muhammad Nuri. Synthesis and characterization of trihydro mono and dihydrobis (indole-3-acetic acid) borate ligands and some of their metal complexes. Iraqi Journal of Science Vol. 56, no. 4A (2015), pp.2762-2772.
https://search.emarefa.net/detail/BIM-651474
American Medical Association (AMA)
Khalil, Asma Muhammad Nuri. Synthesis and characterization of trihydro mono and dihydrobis (indole-3-acetic acid) borate ligands and some of their metal complexes. Iraqi Journal of Science. 2015. Vol. 56, no. 4A, pp.2762-2772.
https://search.emarefa.net/detail/BIM-651474
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 2770-2772
Record ID
BIM-651474