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Synthesis, characterization and reactivity ratios of poly N-(p-bromophenyl)-2-methacrylamide-Co-N-vinyl-2-pyrrolidone
Joint Authors
Thirumoolan, D.
Basha, K. Anver
Kanai, Tapan
Sayf Allah, S. Muhammad
Vetrivel, K.
Abd al-Wasi, K.
Ranjithkumar, B.
Source
Journal of Saudi Chemical Society
Issue
Vol. 20, Issue 2 (31 Mar. 2016), pp.195-200, 6 p.
Publisher
Publication Date
2016-03-31
Country of Publication
Saudi Arabia
No. of Pages
6
Main Subjects
Abstract EN
The methacrylamide monomer, N-(p-bromophenyl)-2-methacrylamide (PBPMA) was synthesized by reacting p-bromoaniline dissolved in ethylmethylketone (EMK) with methacryloyl chloride in the presence of triethylamine.
The copolymers of PBPMA with N-Vinyl-2-pyrrolidone (NVP) were synthesized by free radical solution polymerization using EMK as a solvent at 70 ±1 C and benzoyl peroxide as a free radical initiator.
The copolymerization behavior was studied in a wide composition interval with the mole fractions of PBPMA ranging from 0.20 to 0.80 in the feed.
The copolymers were characterized by FT-IR, 1H NMR, 13C NMR and GPC.
The solubility was tested in various polar and non polar solvents.
The thermogravimetric analysis of the polymers showed that the thermal stability of the copolymer increases with PBPMA content.
The copolymer composition was determined by elemental analysis.
The monomer reactivity ratios were determined by the application of conventional linearization methods such as Fineman–Ross, Kelen–Tudos methods, and a non-linear error-in-variable model (EVM) method using a computer program.
American Psychological Association (APA)
Thirumoolan, D.& Basha, K. Anver& Kanai, Tapan& Sayf Allah, S. Muhammad& Vetrivel, K.& Abd al-Wasi, K.…[et al.]. 2016. Synthesis, characterization and reactivity ratios of poly N-(p-bromophenyl)-2-methacrylamide-Co-N-vinyl-2-pyrrolidone. Journal of Saudi Chemical Society،Vol. 20, no. 2, pp.195-200.
https://search.emarefa.net/detail/BIM-683481
Modern Language Association (MLA)
Thirumoolan, D.…[et al.]. Synthesis, characterization and reactivity ratios of poly N-(p-bromophenyl)-2-methacrylamide-Co-N-vinyl-2-pyrrolidone. Journal of Saudi Chemical Society Vol. 20, no. 2 (Mar. 2016), pp.195-200.
https://search.emarefa.net/detail/BIM-683481
American Medical Association (AMA)
Thirumoolan, D.& Basha, K. Anver& Kanai, Tapan& Sayf Allah, S. Muhammad& Vetrivel, K.& Abd al-Wasi, K.…[et al.]. Synthesis, characterization and reactivity ratios of poly N-(p-bromophenyl)-2-methacrylamide-Co-N-vinyl-2-pyrrolidone. Journal of Saudi Chemical Society. 2016. Vol. 20, no. 2, pp.195-200.
https://search.emarefa.net/detail/BIM-683481
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 200
Record ID
BIM-683481