Liquid Ion exchange method for extraction of Pb (II) as anion by using 15C5 coupled with spectrophotometric determination in different samples
Joint Authors
al-Kubaysi, R. K.
Husayn, Khalil Ibrahim
Hamid, Safa Majid
Source
Journal of Kufa for Chemical Science
Issue
Vol. 1, Issue 10 (30 Nov. 2015), pp.21-37, 17 p.
Publisher
University of Kufa Faculty of Education for Women Department of Chemistry
Publication Date
2015-11-30
Country of Publication
Iraq
No. of Pages
17
Main Subjects
Abstract EN
Separation and extraction of chloroanion complex of Pb2 + by using crown ether 15C5 had been investigated.
This study includes determined hydrochloric acid and sodium chloride concentrations in aqueous phase and Pb2+ ions concentration as well as shaking time, organic solvent effect, interferences, electrolyte salts and methanol effect.
Thermodynamic parameters shown the ion exchange reaction was exothermic.
In addition stoichiometry study shown that the ion pair complex extracted was 1 1:1 Cation: Ligand: Anion.
UV-spectrum of extracting complex show λmax =241nm.
15C5 used as spectrophotometricreagent for the spectrophotometric determination of Pb2 + in different samples, %RSD = 0.00672, D.L = 5.04483 × 10-5 ppm, ε= 2057.85 L.mol-1.cm-1, Sandell’s Sensitivity = 4.86×10-7 μg / cm2.
American Psychological Association (APA)
Hamid, Safa Majid& al-Kubaysi, R. K.& Husayn, Khalil Ibrahim. 2015. Liquid Ion exchange method for extraction of Pb (II) as anion by using 15C5 coupled with spectrophotometric determination in different samples. Journal of Kufa for Chemical Science،Vol. 1, no. 10, pp.21-37.
https://search.emarefa.net/detail/BIM-687440
Modern Language Association (MLA)
Hamid, Safa Majid…[et al.]. Liquid Ion exchange method for extraction of Pb (II) as anion by using 15C5 coupled with spectrophotometric determination in different samples. Journal of Kufa for Chemical Science Vol. 1, no. 10 (Nov. 2015), pp.21-37.
https://search.emarefa.net/detail/BIM-687440
American Medical Association (AMA)
Hamid, Safa Majid& al-Kubaysi, R. K.& Husayn, Khalil Ibrahim. Liquid Ion exchange method for extraction of Pb (II) as anion by using 15C5 coupled with spectrophotometric determination in different samples. Journal of Kufa for Chemical Science. 2015. Vol. 1, no. 10, pp.21-37.
https://search.emarefa.net/detail/BIM-687440
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 37
Record ID
BIM-687440