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Synthesis and characterization of some new mixed-ligand complexes containing schiff base and 3-picoline with some metal salts
Other Title(s)
تحضير و تشخيص بعض المعقدات الفلزية مع ليكاندات مختلطة من قاعدة شف (و -3 بيكولين)
Joint Authors
Muhammad, Mazhar Yunus
Salman, Thair Muhammad
Sarhan, Basimah Muhsin
Source
Ibn al-Haitham Journal for Pure and Applied Science
Issue
Vol. 29, Issue 1 (30 Apr. 2016), pp.102-112, 11 p.
Publisher
University of Baghdad College of Education for Pure Science / Ibn al-Haitham
Publication Date
2016-04-30
Country of Publication
Iraq
No. of Pages
11
Main Subjects
Topics
Abstract EN
Some metal ions (Mn+2, Co+2, Ni+2, Cu+2,Zn+2 and Cd+2) complexes of quodridentats Schiff base derived from (2-hydroxy benzaldehyde and 4,4'-methylenedianiline as primary ligand and 3-picoline (3-pic) secondary ligand have been synthesized and characterized on the basis of their 1H ,13C-NMR, FT-IR, UV-Vis spectroscopy, conductivity measurements, elemental analysis, and magnetic moments, metal to ligands ratio in all complexes has been found to be (1:1:2) (M:Schiff base:3-pic), Schiff base behaves as neutral tetra dentate ligand with (N2,O2) system from the results obtained, the following general formula has suggested for the prepared complexes [M+2(2-mbd)(3-pic)2] and octahedral stereochemistry, Where M+2 = (Mn , Co , Ni , Cu , Zn and Cd), 2-mbd = 2,2'-(1E,1'E)-(4,4'-methylene bis (4,1-phenylene ) bis (azan-1-yl-1-ylidene) bis(methan-1- yl-1-ylidene)diphenol (2-mbd), 3-pic = 3-picoline.
American Psychological Association (APA)
Sarhan, Basimah Muhsin& Muhammad, Mazhar Yunus& Salman, Thair Muhammad. 2016. Synthesis and characterization of some new mixed-ligand complexes containing schiff base and 3-picoline with some metal salts. Ibn al-Haitham Journal for Pure and Applied Science،Vol. 29, no. 1, pp.102-112.
https://search.emarefa.net/detail/BIM-692446
Modern Language Association (MLA)
Sarhan, Basimah Muhsin…[et al.]. Synthesis and characterization of some new mixed-ligand complexes containing schiff base and 3-picoline with some metal salts. Ibn al-Haitham Journal for Pure and Applied Science Vol. 29, no. 1 (2016), pp.102-112.
https://search.emarefa.net/detail/BIM-692446
American Medical Association (AMA)
Sarhan, Basimah Muhsin& Muhammad, Mazhar Yunus& Salman, Thair Muhammad. Synthesis and characterization of some new mixed-ligand complexes containing schiff base and 3-picoline with some metal salts. Ibn al-Haitham Journal for Pure and Applied Science. 2016. Vol. 29, no. 1, pp.102-112.
https://search.emarefa.net/detail/BIM-692446
Data Type
Journal Articles
Language
English
Notes
Includes appendices : p. 107-111
Record ID
BIM-692446