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Synthesis, spectral studies, and theoretical treatment of some new metal complexes with tridentate ligand : schiff and mannich base
Other Title(s)
تحضير، دراسة طيفية و معالجة نظرية لبعض أيونات معقدات جديدة مع ليكاند ثلاثي السن : قاعدة شف و مانخ
Author
Source
Issue
Vol. 13, Issue 2 (30 Jun. 2016), pp.340-351, 12 p.
Publisher
University of Baghdad College of Science for Women
Publication Date
2016-06-30
Country of Publication
Iraq
No. of Pages
12
Main Subjects
Topics
Abstract EN
New metal ions complexes of tridentate ligand (1-((dicyclohexylamino) methyl)-3-(1,5-dimethyl-3-oxo-2-phenyl-2,3-dihydro-1H-pyrzol-4-ylimino) indolin-2-one) have been synthesized and characterized by chemical-physical analysis.
The ligand acts as a tridentate for the complexation reaction with all metal ions.
The new complexes, possessing the general formula [M(L)Cl]Cl where M=[Ni(II), Cu(II), Zn(II), Pd(II), Cd(II), Pt(IV) and Hg(II) ] ,show tetrahedral geometry.
All complexes ,except Pd(II) complex which has a square planar geometry and Pt(IV) which show an octahedral geometry.
The geometry of the prepared compounds has been proposed in another method theoretically by using one of the calculation molecular programs (Hyper chem.-6) program.
Besides the comparison between the experimental results with the theoretical ones, show that the experimental results are so close to the theoretical counterpart.
American Psychological Association (APA)
Baqir, Shayma Rajab. 2016. Synthesis, spectral studies, and theoretical treatment of some new metal complexes with tridentate ligand : schiff and mannich base. Baghdad Science Journal،Vol. 13, no. 2, pp.340-351.
https://search.emarefa.net/detail/BIM-695041
Modern Language Association (MLA)
Baqir, Shayma Rajab. Synthesis, spectral studies, and theoretical treatment of some new metal complexes with tridentate ligand : schiff and mannich base. Baghdad Science Journal Vol. 13, no. 2 (2016), pp.340-351.
https://search.emarefa.net/detail/BIM-695041
American Medical Association (AMA)
Baqir, Shayma Rajab. Synthesis, spectral studies, and theoretical treatment of some new metal complexes with tridentate ligand : schiff and mannich base. Baghdad Science Journal. 2016. Vol. 13, no. 2, pp.340-351.
https://search.emarefa.net/detail/BIM-695041
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 349-351
Record ID
BIM-695041