Hydrothermal synthesis, structural and impedance studies of nano crystalline zinc chromite spinel oxide material

Abstract EN

Zinc chromite (ZnCr2O4) nanocrystalline spinel material was synthesized through hydrothermal method by using zinc nitrate 6-hydrate and chromium nitrate 9-hydrate as precursors.

The synthesized material was characterized for phase identification, crystallinity and surface morphology by X-ray diffraction (XRD) and scanning electron microscopy (SEM).

XRD results showed that hydrothermally as-synthesized products remained poorly crystalline up to 300 C.

Zinc chromite cubic spinel structure developed after calcination at 600 C for 4 h.

Formation of single-phase cubic structure of ZnCr2O4 was also confirmed by Rietveld refinement study with lattice parameter a= 8.2874 A ˚ , and Fd3m space group.

Thermal stability of the developed material was observed by thermogravimetry (TG) and differential thermal analysis (DTA).

Thermal study reveals that ZnCr2O4 is thermally stable above 700 C.

The Fourier transform infrared (FTIR) spectra show the two absorption bands of Cr–O and Zn–O at 490 and 616 cm1 respectively.

These bonds were associated with ZnCr2O4 and indicate the formation of cubic spinel ZnCr2O4 material.

The band gap energy of ZnCr2O4 powder was determined by absorption spectroscopy in ultraviolet–visible