Synthesis, characterisation, XRD, molecular modelling and potential antibacterial studies of Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II) complexes with bidentate azodye ligand
Joint Authors
Mishra, Ramani Ranjan
Sarangi, Ashish Kumar
Mahapatra, Bipin Bihari
Source
Journal of Saudi Chemical Society
Issue
Vol. 20, Issue 6 (30 Nov. 2016), pp.635-643, 9 p.
Publisher
Publication Date
2016-11-30
Country of Publication
Saudi Arabia
No. of Pages
9
Main Subjects
Abstract EN
Six monomeric complexes of Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II) with one O N donor bidentate azodye ligand, 3-(p-tolylazo)-4-hydroxyl-5-methoxybenzaldehyde (LH) (TAHMB) have been prepared.
The complexes have been characterised by analytical, conductance, magnetic susceptibility, IR, electronic spectra, ESR, NMR, X-ray diffraction (Powder pattern) spectra and molecular modelling studies.
The Co (II) and Ni (II) complexes are found to be octahedral, Cu(II) complex is distorted octahedral and a tetrahedral stereochemistry has been assigned to Zn(II), Cd(II) and Hg(II) complexes.
The energy optimised structures Figs.
3–5 are proposed using the semi empirical ZINDO/1 quantum mechanical calculations.
The Ni(II) complex is found to possess an orthorhombic crystal system.
The potential antibacterial studies of the ligand and some metal complexes with gram positive and gram negative bacteria have given encouraging results.
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on behalf of King Saud University.
This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
American Psychological Association (APA)
Mahapatra, Bipin Bihari& Mishra, Ramani Ranjan& Sarangi, Ashish Kumar. 2016. Synthesis, characterisation, XRD, molecular modelling and potential antibacterial studies of Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II) complexes with bidentate azodye ligand. Journal of Saudi Chemical Society،Vol. 20, no. 6, pp.635-643.
https://search.emarefa.net/detail/BIM-716915
Modern Language Association (MLA)
Mahapatra, Bipin Bihari…[et al.]. Synthesis, characterisation, XRD, molecular modelling and potential antibacterial studies of Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II) complexes with bidentate azodye ligand. Journal of Saudi Chemical Society Vol. 20, no. 6 (Nov. 2016), pp.635-643.
https://search.emarefa.net/detail/BIM-716915
American Medical Association (AMA)
Mahapatra, Bipin Bihari& Mishra, Ramani Ranjan& Sarangi, Ashish Kumar. Synthesis, characterisation, XRD, molecular modelling and potential antibacterial studies of Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II) complexes with bidentate azodye ligand. Journal of Saudi Chemical Society. 2016. Vol. 20, no. 6, pp.635-643.
https://search.emarefa.net/detail/BIM-716915
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 642-643
Record ID
BIM-716915