![](/images/graphics-bg.png)
Photochemical study of 2- (6-methoxynaphthalen-2-yl) propanoic acid iron (III) in different organic solvents
Other Title(s)
دراسة الكيمياء الضوئية لمعقد الحديد الثلاثي مع الليكاند ثنائي السن 2-(6-methoxynapthalen-2-yl) propanoic acid في مذيبات عضوية مختلفة
Joint Authors
Husayn, Zaynab
Ibrahim, Farah M.
Fadil, Duha H.
al-Amiri, Ahmad
Yusuf, Imad
Source
Engineering and Technology Journal
Issue
Vol. 34, Issue 3B (31 Mar. 2016), pp.358-366, 9 p.
Publisher
Publication Date
2016-03-31
Country of Publication
Iraq
No. of Pages
9
Main Subjects
Abstract EN
The photochemistry of chelate complex 2-(6-methoxynaphthalen-2-yl) propanoic acid iron (III) Fe(L)3 was studied in three polar aprotic solvents: Dimethyl sulfoxide (DMSO), Dimethyl form amide (DMF), Acetone (Ac).
Monochromatic light of wavelength 311 nm was utilized for the irradiation-process at 25oC.
UV-VIS changes demonstrated an intraoxidation-reduction response happening amid the photolysis of Fe(L)3 complex, with homolytic scission of Fe-L bond.
Quantum yield (Qd), rate of photodecomposition and reactivity proportion (k2/k-1) was resolved in every used solvent.
These values dependably increment as polarity of the solvent increments and take after the order: DMSO > DMF > Ac.
The mechanism of photodecomposition of this complex under the connected conditions was proposed.
American Psychological Association (APA)
Ibrahim, Farah M.& Husayn, Zaynab& Fadil, Duha H.& al-Amiri, Ahmad& Yusuf, Imad. 2016. Photochemical study of 2- (6-methoxynaphthalen-2-yl) propanoic acid iron (III) in different organic solvents. Engineering and Technology Journal،Vol. 34, no. 3B, pp.358-366.
https://search.emarefa.net/detail/BIM-729000
Modern Language Association (MLA)
Ibrahim, Farah M.…[et al.]. Photochemical study of 2- (6-methoxynaphthalen-2-yl) propanoic acid iron (III) in different organic solvents. Engineering and Technology Journal Vol. 34, no. 3B (2016), pp.358-366.
https://search.emarefa.net/detail/BIM-729000
American Medical Association (AMA)
Ibrahim, Farah M.& Husayn, Zaynab& Fadil, Duha H.& al-Amiri, Ahmad& Yusuf, Imad. Photochemical study of 2- (6-methoxynaphthalen-2-yl) propanoic acid iron (III) in different organic solvents. Engineering and Technology Journal. 2016. Vol. 34, no. 3B, pp.358-366.
https://search.emarefa.net/detail/BIM-729000
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 365-366
Record ID
BIM-729000