Laboratory study of MgO preparation from Iraqi dolomite by leach-precipitation-pyrohydrolysis process
Other Title(s)
دراسة مختبرية لتحضير أوكسيد المغنيسيوم من الدولومايت العراقي بطريقة الإذابة-الترسيب-التحلل الحراري
Joint Authors
Mustafa, Ala Muhammad Khalil
al-Dahhan, Dalya Khalid
Khachik, Tanya V.
Source
Iraqi Bulletin of Geology and Mining
Issue
Vol. 10, Issue 3 (31 Dec. 2014), pp.83-107, 25 p.
Publisher
Ministry of Industry and Minerals Iraqi Geological Survey
Publication Date
2014-12-31
Country of Publication
Iraq
No. of Pages
25
Main Subjects
Earth Sciences, Water and Environment
Abstract EN
In this study, a three-process approach was applied for the extraction of Magnesia (MgO) from Iraqi dolomite.
The first process comprises leaching of (– 2 mm) raw dolomite in 25% solid by 22% HCl aqueous solution for 10 minutes at room temperature, extracts 99.68% of MgO in the dolomite ore.
The second process, which is a separation process, includes twosteps (hydration and carbonation) for the separation of calcium as Precipitated Calcium Carbonate (PCC, 1st stage) of 90.1% purity and a magnesium recovery of 92.8% as dissolved MgCl2.
Hydration was carried out by adding 55% by weight ratio of calcined dolomite (dolime)/ leached dolomite at 70 °C for 60 minute; this was followed by carbonation of the slurry formed by CO2 gas at a pressure of 2 bars for 100 minutes at room temperature.
The MgCl2 solution produced was subjected for evaporation to remove the dissolved Calcium Bicarbonate by precipitation as (PCC, 2nd stage) with a purity of 97%.
The purified brine was further evaporated till dry salt of MgCl2.6H2O (Bischofite) was obtained, and then subjected for pyrohydrolysis, which was the third process, at 650 °C for 60 minutes.
22% HCl was regenerated with a product of 95.48% MgO purity after washing with water and drying.
American Psychological Association (APA)
Mustafa, Ala Muhammad Khalil& al-Dahhan, Dalya Khalid& Khachik, Tanya V.. 2014. Laboratory study of MgO preparation from Iraqi dolomite by leach-precipitation-pyrohydrolysis process. Iraqi Bulletin of Geology and Mining،Vol. 10, no. 3, pp.83-107.
https://search.emarefa.net/detail/BIM-748146
Modern Language Association (MLA)
Mustafa, Ala Muhammad Khalil…[et al.]. Laboratory study of MgO preparation from Iraqi dolomite by leach-precipitation-pyrohydrolysis process. Iraqi Bulletin of Geology and Mining Vol. 10, no. 3 (2014), pp.83-107.
https://search.emarefa.net/detail/BIM-748146
American Medical Association (AMA)
Mustafa, Ala Muhammad Khalil& al-Dahhan, Dalya Khalid& Khachik, Tanya V.. Laboratory study of MgO preparation from Iraqi dolomite by leach-precipitation-pyrohydrolysis process. Iraqi Bulletin of Geology and Mining. 2014. Vol. 10, no. 3, pp.83-107.
https://search.emarefa.net/detail/BIM-748146
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 106-107
Record ID
BIM-748146