Kinetic and mechanistic studies for the gas-phase reaction of ozone with 2, 3-dimethyl-2-butene and 1, 3-butadiene
Other Title(s)
دراسات حركية و ميكانيكية لتفاعل الطور الغازي بين الأوزون و كل من المركب 2, 3-ثنائي مثيل-2-بيوتين و المركب 1, 3-بيوتادايين
Author
Ismail, Ismail Abd al-Sattar al-Mulla
Source
Issue
Vol. 14, Issue 3 (30 Sep. 2017), pp.547-556, 10 p.
Publisher
University of Baghdad College of Science for Women
Publication Date
2017-09-30
Country of Publication
Iraq
No. of Pages
10
Main Subjects
Topics
Abstract EN
The reactions of ozone with 2,3-Dimethyl-2-Butene (CH3)2C=C(CH3)2 and 1,3-Butadiene CH2=CHCH=CH2 have been investigated under atmospheric conditions at 298±3K in air using both relative and absolute rate techniques, and the measured rate coefficients are found to be in good agreement in both techniques used.
The obtained results show the addition of ozone to the double bond in these compounds and how it acts as function of the methyl group substituent situated on the double bond.
The yields of all the main products have been determined using FTIR and GC-FID and the product studies of these reactions establish a very good idea for the decomposition pathways for the primary formed compounds (ozonides) and give a good information for the effect of the methyl group on the degradation pathways.
The results have been discussed from the view point of their importance in the atmospheric oxidation of these pollutants.-
American Psychological Association (APA)
Ismail, Ismail Abd al-Sattar al-Mulla. 2017. Kinetic and mechanistic studies for the gas-phase reaction of ozone with 2, 3-dimethyl-2-butene and 1, 3-butadiene. Baghdad Science Journal،Vol. 14, no. 3, pp.547-556.
https://search.emarefa.net/detail/BIM-759921
Modern Language Association (MLA)
Ismail, Ismail Abd al-Sattar al-Mulla. Kinetic and mechanistic studies for the gas-phase reaction of ozone with 2, 3-dimethyl-2-butene and 1, 3-butadiene. Baghdad Science Journal Vol. 14, no. 3 (2017), pp.547-556.
https://search.emarefa.net/detail/BIM-759921
American Medical Association (AMA)
Ismail, Ismail Abd al-Sattar al-Mulla. Kinetic and mechanistic studies for the gas-phase reaction of ozone with 2, 3-dimethyl-2-butene and 1, 3-butadiene. Baghdad Science Journal. 2017. Vol. 14, no. 3, pp.547-556.
https://search.emarefa.net/detail/BIM-759921
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 554-555
Record ID
BIM-759921