1,3-bis(4-methylbenzyl)imidazol-2-ylidene silver(I) chloride catalyzed carboxylative coupling of terminal alkynes, butyl iodide and carbon dioxide
Joint Authors
Sun, Jing
Zhou, Mingdong
Zhang, Zhi-Zhi
Mi, Rui Jie
Fang, Xiang-Chen
Guo, Fang Jie
Source
Journal of Saudi Chemical Society
Issue
Vol. 21, Issue 6 (30 Sep. 2017), pp.685-690, 6 p.
Publisher
Publication Date
2017-09-30
Country of Publication
Saudi Arabia
No. of Pages
6
Main Subjects
Topics
Abstract EN
The N-heterocyclic carbene silver(I) complex 1,3-bis(4-methylbenzyl)imidazol-2-ylidene silver chloride was applied as the effective catalyst for the three-component carboxylative coupling of terminal alkynes, butyl iodide and carbon dioxide.
The reaction proved to be highly efficient when using 2 mol% of 1,3-bis(4-methylbenzyl)imidazol-2-ylidene silver(I) chloride as the catalyst in the presence of 1.5 equiv.
of Cs2CO3 as the base in DMF.
This reaction shows good selectivity and substituent-loading capability, in which various functionalized 2-alkynoates were obtained in good yields under very mild conditions.
American Psychological Association (APA)
Zhang, Zhi-Zhi& Mi, Rui Jie& Guo, Fang Jie& Sun, Jing& Zhou, Mingdong& Fang, Xiang-Chen. 2017. 1,3-bis(4-methylbenzyl)imidazol-2-ylidene silver(I) chloride catalyzed carboxylative coupling of terminal alkynes, butyl iodide and carbon dioxide. Journal of Saudi Chemical Society،Vol. 21, no. 6, pp.685-690.
https://search.emarefa.net/detail/BIM-762694
Modern Language Association (MLA)
Guo, Fang Jie…[et al.]. 1,3-bis(4-methylbenzyl)imidazol-2-ylidene silver(I) chloride catalyzed carboxylative coupling of terminal alkynes, butyl iodide and carbon dioxide. Journal of Saudi Chemical Society Vol. 21, no. 6 (Sep. 2017), pp.685-690.
https://search.emarefa.net/detail/BIM-762694
American Medical Association (AMA)
Zhang, Zhi-Zhi& Mi, Rui Jie& Guo, Fang Jie& Sun, Jing& Zhou, Mingdong& Fang, Xiang-Chen. 1,3-bis(4-methylbenzyl)imidazol-2-ylidene silver(I) chloride catalyzed carboxylative coupling of terminal alkynes, butyl iodide and carbon dioxide. Journal of Saudi Chemical Society. 2017. Vol. 21, no. 6, pp.685-690.
https://search.emarefa.net/detail/BIM-762694
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 689-690
Record ID
BIM-762694