Synthesis, structural and spectroscopic study of complexes of tetradentate schiff base derived from malonyl dihydrazide with Cr (III)‎, Mn (II)‎, Co (II)‎, Cu (II)‎ and Zn (II)‎ ions

Abstract EN

This paper describes the synthesis of a new derivative dihydro-3H-indol-3-ylidene propane dihydrazide [L], which have been obtained from the reaction between malonyl di-hydrazide and an ethanollic solution of isatin.

Tetradentatemacrocyclic ligand [L] was characterized by (C.H.N), (FT-IR), (UV-Vis), and 1H.NMR.A series of the used metal complexes have been synthesized by the prepared ligand [L] reaction with some transition metal ions.

The isolated complexes were Cr(III), Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) also characterized using different techniques such as (FT-IR), and (UV-Vis) spectroscopies, (C.H.N), flam atomic absorption in addition to the magnetic susceptibility and molar conductivity measurement.

Al complexes were octahedral in geometry except for Zn (II) complex, which was tetrahedral.