Synthesis and characterization of transition metal complexes with macrocyclic ligand
Other Title(s)
تحضير و تشخيص مركبات حلقية كبيرة مع بعض العناصر الانتقالية
Dissertant
Thesis advisor
University
Mutah University
Faculty
Faculty of Science
Department
Department of Chemistry
University Country
Jordan
Degree
Master
Degree Date
2008
English Abstract
This thesis is concerned with the reactions of macrocyclic Schiff base ligands derived from the condensation of 2,6-diformylpyridine and different diamines, namely, 2,6-diaminopyridine (dap), 1,2- phenylenediamine (daPh), trans-1,2-diaminocyclohexane (dach) and ethylenediamine (en) with some transition metal ions using template method.
The metal ions used are Pd(II), Pt(II), Rh(III), Pd(IV), and Pt(IV).
The formula obtained for the complexes are: PdC18H18N6Br2, PtC18H18N6Br2, PdC18H18N6Cl4.0.5H2O, PtC24H16N8Cl2.6CH3CN, RhC24H16N8Cl3.4.5H2O, Pd2C36H24N12(BF4)4.8H2O, PtC36H24N12Br2, PdC26H18N6Cl2.0.5H2O, PdC26H18N6Br2.H2O, PdC26H18N6Cl4.1.5H2O, PtC26H18N6Br2, PtC26H18N6Cl4, RhC26H18N6Cl3, PdC26H30N6Cl2, PdC26H30N6Br2.0.5H2O, PtC26H30N6Br2, PtC26H30N6Cl4.
However, the reaction of 2,6-diformylpyridine with dap afforded an open chain Schiff base complexes: Pd2C17H15N7Cl4.CH3CN.1.5H2O, Pd2C17H15N7Br4.0.5.
PhCN.3H2O and Pt2C17H15N7Cl8.PhCN.5H2O.
The isolated compounds are characterized on the basis of their melting points, elemental analyses, conductivity measurements, nuclear magnetic resonance, FTIR and electronic absorption spectra
Main Subjects
No. of Pages
81
Table of Contents
Table of contents.
Abstract.
Abstract in Arabic.
Chapter One : Introduction
Chapter Two : Experimental.
Chapter Three : Results and discussion.
References.
American Psychological Association (APA)
al-Mabrih, Ala. (2008). Synthesis and characterization of transition metal complexes with macrocyclic ligand. (Master's theses Theses and Dissertations Master). Mutah University, Jordan
https://search.emarefa.net/detail/BIM-786525
Modern Language Association (MLA)
al-Mabrih, Ala. Synthesis and characterization of transition metal complexes with macrocyclic ligand. (Master's theses Theses and Dissertations Master). Mutah University. (2008).
https://search.emarefa.net/detail/BIM-786525
American Medical Association (AMA)
al-Mabrih, Ala. (2008). Synthesis and characterization of transition metal complexes with macrocyclic ligand. (Master's theses Theses and Dissertations Master). Mutah University, Jordan
https://search.emarefa.net/detail/BIM-786525
Language
English
Data Type
Arab Theses
Record ID
BIM-786525
