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Highly efficient transition metal-free coupling of acid chlorides with terminal alkynes in (bmim) Br : a rapid route to access ynones using MgCl2
Author
Source
Journal of Saudi Chemical Society
Issue
Vol. 22, Issue 3 (31 Mar. 2018), pp.329-336, 8 p.
Publisher
Publication Date
2018-03-31
Country of Publication
Saudi Arabia
No. of Pages
8
Main Subjects
Abstract EN
A simple, mild, highly efficient and transition metal-free protocol for synthesis of ynones in an ionic liquid is described.
In this approach, the coupling reaction of different acid chlorides with terminal alkynes was efficiently carried out using 0.05 mol% MgCl2 in the presence of triethylamine in [bmim]Br at room temperature to afford the corresponding ynones in good to excellent yields.
This method is highly efficient for various acid chlorides and alkynes including aliphatic, aromatic, and heteroaromatic substrates bearing different functional groups.
The influence of some parameters in this reaction including type of ionic liquid, base and catalyst has been discussed.
American Psychological Association (APA)
Rad, Muhammad Navid Sultani. 2018. Highly efficient transition metal-free coupling of acid chlorides with terminal alkynes in (bmim) Br : a rapid route to access ynones using MgCl2. Journal of Saudi Chemical Society،Vol. 22, no. 3, pp.329-336.
https://search.emarefa.net/detail/BIM-790233
Modern Language Association (MLA)
Rad, Muhammad Navid Sultani. Highly efficient transition metal-free coupling of acid chlorides with terminal alkynes in (bmim) Br : a rapid route to access ynones using MgCl2. Journal of Saudi Chemical Society Vol. 22, no. 3 (Mar. 2018), pp.329-336.
https://search.emarefa.net/detail/BIM-790233
American Medical Association (AMA)
Rad, Muhammad Navid Sultani. Highly efficient transition metal-free coupling of acid chlorides with terminal alkynes in (bmim) Br : a rapid route to access ynones using MgCl2. Journal of Saudi Chemical Society. 2018. Vol. 22, no. 3, pp.329-336.
https://search.emarefa.net/detail/BIM-790233
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 335-336
Record ID
BIM-790233