Synthesis and coordination chemistry of boron-functionalized poly (pyrazolylpyridyl) borate with Ln (III) metals
Other Title(s)
التركيب و الخصائص الكيميائية لمركبات البورون مع بايروزول بيريدين و فلزات اللانثانات
Joint Authors
Ward, Michael D.
Al-Rasbi, Nawal K.
Source
Sultan Qaboos University Journal for Science
Issue
Vol. 22, Issue 2 (31 Dec. 2017), pp.73-80, 8 p.
Publisher
Sultan Qaboos University College of Science
Publication Date
2017-12-31
Country of Publication
Oman
No. of Pages
8
Main Subjects
Abstract EN
new family of lanthanide/boron-based complexes have been synthesized from the novel substituted poly(pyrazolylpyridyl)borate ligand containing phenyl substituents on the boron atom Ph2Bppy (L).
The complexes have been fully characterized by analytical and spectroscopic methods.
The single crystal X-ray structure and mass spectroscopy reveal the isostructural dinuclear complexes: [Ln2(L)2(NO3)2(OH)2] where Ln = Eu, Gd or Tb.
Upon excitation of the Ln(III) complexes in DCM, their luminescence spectra display narrow f–f transitions.
It is found that the ligand can efficiently sensitize the Tb(III) complex because of the better triplet state energy match to the Tb(III)–5D0 excited states.
American Psychological Association (APA)
Al-Rasbi, Nawal K.& Ward, Michael D.. 2017. Synthesis and coordination chemistry of boron-functionalized poly (pyrazolylpyridyl) borate with Ln (III) metals. Sultan Qaboos University Journal for Science،Vol. 22, no. 2, pp.73-80.
https://search.emarefa.net/detail/BIM-812497
Modern Language Association (MLA)
Al-Rasbi, Nawal K.& Ward, Michael D.. Synthesis and coordination chemistry of boron-functionalized poly (pyrazolylpyridyl) borate with Ln (III) metals. Sultan Qaboos University Journal for Science Vol. 22, no. 2 (2017), pp.73-80.
https://search.emarefa.net/detail/BIM-812497
American Medical Association (AMA)
Al-Rasbi, Nawal K.& Ward, Michael D.. Synthesis and coordination chemistry of boron-functionalized poly (pyrazolylpyridyl) borate with Ln (III) metals. Sultan Qaboos University Journal for Science. 2017. Vol. 22, no. 2, pp.73-80.
https://search.emarefa.net/detail/BIM-812497
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 79-80
Record ID
BIM-812497