Synthesis and characterization of feII, coII, niII, Cu11 and Zu11 complexes with dithiocarbamate and n-donor ligands

Joint Authors

Ali, Asma Basim

Source

Ibn al-Haitham Journal for Pure and Applied Science

Issue

Vol. 30, Issue 3 (31 Dec. 2017), pp.130-149, 20 p.

Publisher

University of Baghdad College of Education for Pure Science / Ibn al-Haitham

Publication Date

2017-12-31

Country of Publication

Iraq

No. of Pages

20

Main Subjects

Natural & Life Sciences (Multidisciplinary)

Abstract EN

New complexes of first series of transition metals with P-amino benzene ditliiocarbamate of the general formula [M(PABdtc):] and [ M(PABdtc)2(L)n] M=Fe( II ).Co( II ),Ni( II ) .Cu(II)andZn(II).

PABdtc = Paraammo benzene ditliiocarbamate ,n=2 when L= Py.y-Pic.iso qunoline .3,5- lutidme n=lwhen L= 1.10-phenanthroline, en.

2, 2bipy.and the type(R)4N[Ni(PABdtc)3] R= methyl, ethyl are prepared.

Physico chemical characterization of these complexes was applied using magnetic susceptibility measurements, molar conductance .

Infrared and electronic spectra.

Metal content measurements, molar conductance indicate complexes of the type [M(PABdtc)2] and [M(PABdtc)2(L)n] are non-electrolyte while complexes of the type (R)4N[Ni(PABdtc)3] are 1:1 electrolyte.

Magnetic moment and electronic spectra indicate that the complexes of the type [M(PABdtc)2] are tetrahedral geometry while the complexes of the type [M(PABdtc)2(L)n] and (R)4N[Ni(PABdtc)3] have octahedral geometry-.

American Psychological Association (APA)

Muhammad, Muhammad Jassam& Ali, Asma Basim. 2017. Synthesis and characterization of feII, coII, niII, Cu11 and Zu11 complexes with dithiocarbamate and n-donor ligands. Ibn al-Haitham Journal for Pure and Applied Science،Vol. 30, no. 3, pp.130-149.
https://search.emarefa.net/detail/BIM-851849

Modern Language Association (MLA)

Muhammad, Muhammad Jassam& Ali, Asma Basim. Synthesis and characterization of feII, coII, niII, Cu11 and Zu11 complexes with dithiocarbamate and n-donor ligands. Ibn al-Haitham Journal for Pure and Applied Science Vol. 30, no. 3 (2017), pp.130-149.
https://search.emarefa.net/detail/BIM-851849

American Medical Association (AMA)

Muhammad, Muhammad Jassam& Ali, Asma Basim. Synthesis and characterization of feII, coII, niII, Cu11 and Zu11 complexes with dithiocarbamate and n-donor ligands. Ibn al-Haitham Journal for Pure and Applied Science. 2017. Vol. 30, no. 3, pp.130-149.
https://search.emarefa.net/detail/BIM-851849

Data Type

Journal Articles

Language

English

Notes

Includes appendices : p. 135-149

Record ID

BIM-851849