Synthesis and characterization of feII, coII, niII, Cu11 and Zu11 complexes with dithiocarbamate and n-donor ligands
Joint Authors
Source
Ibn al-Haitham Journal for Pure and Applied Science
Issue
Vol. 30, Issue 3 (31 Dec. 2017), pp.130-149, 20 p.
Publisher
University of Baghdad College of Education for Pure Science / Ibn al-Haitham
Publication Date
2017-12-31
Country of Publication
Iraq
No. of Pages
20
Main Subjects
Natural & Life Sciences (Multidisciplinary)
Abstract EN
New complexes of first series of transition metals with P-amino benzene ditliiocarbamate of the general formula [M(PABdtc):] and [ M(PABdtc)2(L)n] M=Fe( II ).Co( II ),Ni( II ) .Cu(II)andZn(II).
PABdtc = Paraammo benzene ditliiocarbamate ,n=2 when L= Py.y-Pic.iso qunoline .3,5- lutidme n=lwhen L= 1.10-phenanthroline, en.
2, 2bipy.and the type(R)4N[Ni(PABdtc)3] R= methyl, ethyl are prepared.
Physico chemical characterization of these complexes was applied using magnetic susceptibility measurements, molar conductance .
Infrared and electronic spectra.
Metal content measurements, molar conductance indicate complexes of the type [M(PABdtc)2] and [M(PABdtc)2(L)n] are non-electrolyte while complexes of the type (R)4N[Ni(PABdtc)3] are 1:1 electrolyte.
Magnetic moment and electronic spectra indicate that the complexes of the type [M(PABdtc)2] are tetrahedral geometry while the complexes of the type [M(PABdtc)2(L)n] and (R)4N[Ni(PABdtc)3] have octahedral geometry-.
American Psychological Association (APA)
Muhammad, Muhammad Jassam& Ali, Asma Basim. 2017. Synthesis and characterization of feII, coII, niII, Cu11 and Zu11 complexes with dithiocarbamate and n-donor ligands. Ibn al-Haitham Journal for Pure and Applied Science،Vol. 30, no. 3, pp.130-149.
https://search.emarefa.net/detail/BIM-851849
Modern Language Association (MLA)
Muhammad, Muhammad Jassam& Ali, Asma Basim. Synthesis and characterization of feII, coII, niII, Cu11 and Zu11 complexes with dithiocarbamate and n-donor ligands. Ibn al-Haitham Journal for Pure and Applied Science Vol. 30, no. 3 (2017), pp.130-149.
https://search.emarefa.net/detail/BIM-851849
American Medical Association (AMA)
Muhammad, Muhammad Jassam& Ali, Asma Basim. Synthesis and characterization of feII, coII, niII, Cu11 and Zu11 complexes with dithiocarbamate and n-donor ligands. Ibn al-Haitham Journal for Pure and Applied Science. 2017. Vol. 30, no. 3, pp.130-149.
https://search.emarefa.net/detail/BIM-851849
Data Type
Journal Articles
Language
English
Notes
Includes appendices : p. 135-149
Record ID
BIM-851849