Synthesis and characterization of new bidentate schiff base ligand type (NO) donor atoms derived from Isatin and 3-amino benzoic acid and its complexes with Co(II), Cu(II), Cd(II) and Hg(II) ions
Author
Source
Ibn al-Haitham Journal for Pure and Applied Science
Issue
Vol. 30, Issue 3 (31 Dec. 2017), pp.158-169, 12 p.
Publisher
University of Baghdad College of Education for Pure Science / Ibn al-Haitham
Publication Date
2017-12-31
Country of Publication
Iraq
No. of Pages
12
Main Subjects
Natural & Life Sciences (Multidisciplinary)
Abstract EN
New bidentate Schiff base ligand (L) namely [(Z)-3-(2-oxoindolin-3- ylildeneamino)benzoic acid] type (NO) was prepared via condensation of isatin and 3-amino benzoic acid in ethanol as a solvent in existence of drops of (glac.
CH3COOH).
The new ligand (L) was characterized base on elemental micro analysis.
FT-IR.
UV-Vis, !H-NMR spectra along with melting point.
Ligand complexes in general formula [M(L)2Cl2].
H2O, where: MII= Co.
Cu.
Cd.
and Hg; L= C15H10 N2O3 were synthesized and identified by FT-IR.
UV-Vis.
*H-NMR (for Cd complex only) spectra, atomic absorption, chloride content along with molar conductivity and magnetic susceptibility.
It was found that the ligand behaves as bidentate on complexation via (N) atom of inline group and (O) atom of carbonyl group of five member ring.
The electronic spectral data and µeff values (Co, Cu) of the complexes exhibited octahedral geometry around Co11, Cu11.
CdII.
Hg11 metal ions.
The results of antibacterial activity showed that only Hg(II) complex has high activity (35 mm) for staphylococcus aureas.
American Psychological Association (APA)
al-Kam, Hiam Hadi. 2017. Synthesis and characterization of new bidentate schiff base ligand type (NO) donor atoms derived from Isatin and 3-amino benzoic acid and its complexes with Co(II), Cu(II), Cd(II) and Hg(II) ions. Ibn al-Haitham Journal for Pure and Applied Science،Vol. 30, no. 3, pp.158-169.
https://search.emarefa.net/detail/BIM-851850
Modern Language Association (MLA)
al-Kam, Hiam Hadi. Synthesis and characterization of new bidentate schiff base ligand type (NO) donor atoms derived from Isatin and 3-amino benzoic acid and its complexes with Co(II), Cu(II), Cd(II) and Hg(II) ions. Ibn al-Haitham Journal for Pure and Applied Science Vol. 30, no. 3 (2017), pp.158-169.
https://search.emarefa.net/detail/BIM-851850
American Medical Association (AMA)
al-Kam, Hiam Hadi. Synthesis and characterization of new bidentate schiff base ligand type (NO) donor atoms derived from Isatin and 3-amino benzoic acid and its complexes with Co(II), Cu(II), Cd(II) and Hg(II) ions. Ibn al-Haitham Journal for Pure and Applied Science. 2017. Vol. 30, no. 3, pp.158-169.
https://search.emarefa.net/detail/BIM-851850
Data Type
Journal Articles
Language
English
Notes
Includes appendices : p. 163-169
Record ID
BIM-851850