Pyridine solvated dioxouranium complex with salen ligand : synthesis, characterization and luminescence properties
Joint Authors
Kruszynski, Rafal
Azzam, Muhammad
al-Rayyis, Suud I.
Trzesowska Kruszynska, Agata
Lokanath, N. K.
Adil, S. F.
Source
Journal of Saudi Chemical Society
Issue
Vol. 23, Issue 5 (31 Jul. 2019), pp.636-641, 6 p.
Publisher
Publication Date
2019-07-31
Country of Publication
Saudi Arabia
No. of Pages
6
Main Subjects
Topics
Abstract EN
A new derivative of dioxouranium(VI) salen complex, [UO2(L)(pyridine)], where [L = N,N′-Bis(2-hydroxybenzylidene)-2,2-dimethyl-1,3-propanediamine] is synthesized and characterized by elemental analysis (C, H, N), FT-IR, ESI-MS spectrometry, UV/Vis, fluorescence, 1H and 13C NMR spectroscopy and thermal gravimetric (TG) study.
Furthermore, the single crystal X-ray diffraction measurements of the complex were carried out at 100 and 273 K.
The crystal structure measurements revealed that the complex has distorted pentagonal bipyramidal geometry with uranium atom located at the centre and bonded to two phenoxy oxygen and two azomethine nitrogen in tetradenate fashion and one nitrogen from pyridine making it seven coordinated.
In addition, the photoluminescence property of the complex was also recorded.
American Psychological Association (APA)
Azzam, Muhammad& al-Rayyis, Suud I.& Trzesowska Kruszynska, Agata& Kruszynski, Rafal& Adil, S. F.& Lokanath, N. K.. 2019. Pyridine solvated dioxouranium complex with salen ligand : synthesis, characterization and luminescence properties. Journal of Saudi Chemical Society،Vol. 23, no. 5, pp.636-641.
https://search.emarefa.net/detail/BIM-889263
Modern Language Association (MLA)
Azzam, Muhammad…[et al.]. Pyridine solvated dioxouranium complex with salen ligand : synthesis, characterization and luminescence properties. Journal of Saudi Chemical Society Vol. 23, no. 5 (Jul. 2019), pp.636-641.
https://search.emarefa.net/detail/BIM-889263
American Medical Association (AMA)
Azzam, Muhammad& al-Rayyis, Suud I.& Trzesowska Kruszynska, Agata& Kruszynski, Rafal& Adil, S. F.& Lokanath, N. K.. Pyridine solvated dioxouranium complex with salen ligand : synthesis, characterization and luminescence properties. Journal of Saudi Chemical Society. 2019. Vol. 23, no. 5, pp.636-641.
https://search.emarefa.net/detail/BIM-889263
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 640-641
Record ID
BIM-889263