Spectrophotometric determination of the stoichiometry of cobalt (II) and copper (II) salicylhydroxamate complexes
Joint Authors
Ahmed, E. A.
Abd al-Aziz, M. E.
Ibrahim, R. A.
Source
Journal of Science and Technology : in Natural and Medical Sciences
Issue
Vol. 19, Issue 2 (31 Dec. 2018), pp.1-9, 9 p.
Publisher
Sudan University of Science and Technology Deanship of Scientific Research
Publication Date
2018-12-31
Country of Publication
Sudan
No. of Pages
9
Main Subjects
Abstract EN
Salicylhydroxamic acid was prepared by coupling reaction of methyl salicylate and free hydroxylamine, precipitated by acidification and recrystallized by hot water/ acetic acid it was characterizedby melting point, iron and vanadiumcolor test and FT-IR absorption bands at 3260cm-1 (OH), 1663 cm-1 (C=O), and 900 cm-1 (N-O) and 1H-NMR characteristic peak of the proton of the hydroxyl group attached to the nitrogen atom in the region 9.566 – 9.762 ppm.
the shifting of the resonance signal of hydroxyl proton to lower field supports intermolecular hydrogen bonding.
the peak proton of aromatic ring appears in the region 7.699 – 7.714 ppm.
the peakprotons of – NH appears in the region 3.772 – 3.783 ppm.The 13C NMR spectra exhibit absorption signal due to carbonyl (C=O) group at nearly 166.118 ppm.
the chemical shifts of aromatic carbons appear in the region of 133.329 – 127.148 ppm.
the complexation ofsalicylhydroxamic acideither withCo2+ orCu2+cation wasboth determined by continuous variationmethod.
Spectrophotometric analysis for determination of Co2+ and Cu2+salicylhydroxamate complexes was based on formation of colored complexes in weak acidic media.
the produced colored complexes of Co2+ andCu2+showed maximum absorption at λmax510 nmand 385nm respectively.
The mole ratio of complexes were determined in different chemical environments,and found to be in ratio of 1:3 and 1:1( M:L), respectively.
American Psychological Association (APA)
Ibrahim, R. A.& Ahmed, E. A.& Abd al-Aziz, M. E.. 2018. Spectrophotometric determination of the stoichiometry of cobalt (II) and copper (II) salicylhydroxamate complexes. Journal of Science and Technology : in Natural and Medical Sciences،Vol. 19, no. 2, pp.1-9.
https://search.emarefa.net/detail/BIM-892057
Modern Language Association (MLA)
Ibrahim, R. A.…[et al.]. Spectrophotometric determination of the stoichiometry of cobalt (II) and copper (II) salicylhydroxamate complexes. Journal of Science and Technology : in Natural and Medical Sciences Vol. 19, no. 2 (2018), pp.1-9.
https://search.emarefa.net/detail/BIM-892057
American Medical Association (AMA)
Ibrahim, R. A.& Ahmed, E. A.& Abd al-Aziz, M. E.. Spectrophotometric determination of the stoichiometry of cobalt (II) and copper (II) salicylhydroxamate complexes. Journal of Science and Technology : in Natural and Medical Sciences. 2018. Vol. 19, no. 2, pp.1-9.
https://search.emarefa.net/detail/BIM-892057
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 8-9
Record ID
BIM-892057