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Synthesis of achiral NCN pincer Pt (II) and Pd (II) complexes and catalytic application in the Suzuki-Miyaura reaction
Joint Authors
Hao, Xin Qi
Zhu, Xinju
Wang, Yan Bing
Zhu, Zhi Hui
Zhao, Xue Mei
Liu, Xiao Yan
Song, Bing
Source
Journal of Saudi Chemical Society
Issue
Vol. 23, Issue 1 (31 Jan. 2019), pp.104-110, 7 p.
Publisher
Publication Date
2019-01-31
Country of Publication
Saudi Arabia
No. of Pages
7
Main Subjects
Topics
Abstract EN
A series of platinum and palladium pincer complexes supported by achiral 1,3-bis(20-imi dazolinyl)benzene-based NCN ligands have been prepared via direct C2 metalation.
Meanwhile, ligand precursor 3b and Pt(II) complex 4b were characterized by crystallographic studies, which reveals that the platinum atom in 4b adopts a distorted-square-planar geometry.
The Pd(II) pincer complexes 5b was found to be an efficient catalyst for Suzuki cross-coupling reaction of aryl bromides and phenylboronic acid under air.
In the presence of 0.5 mol % of Pd(II) 5b in DMF/K3PO43H2O for 8 h, the corresponding biaryl products could be obtained in 24–99 % yields.
American Psychological Association (APA)
Wang, Yan Bing& Liu, Xiao Yan& Zhu, Zhi Hui& Zhao, Xue Mei& Song, Bing& Zhu, Xinju…[et al.]. 2019. Synthesis of achiral NCN pincer Pt (II) and Pd (II) complexes and catalytic application in the Suzuki-Miyaura reaction. Journal of Saudi Chemical Society،Vol. 23, no. 1, pp.104-110.
https://search.emarefa.net/detail/BIM-892750
Modern Language Association (MLA)
Wang, Yan Bing…[et al.]. Synthesis of achiral NCN pincer Pt (II) and Pd (II) complexes and catalytic application in the Suzuki-Miyaura reaction. Journal of Saudi Chemical Society Vol. 23, no. 1 (Jan. 2019), pp.104-110.
https://search.emarefa.net/detail/BIM-892750
American Medical Association (AMA)
Wang, Yan Bing& Liu, Xiao Yan& Zhu, Zhi Hui& Zhao, Xue Mei& Song, Bing& Zhu, Xinju…[et al.]. Synthesis of achiral NCN pincer Pt (II) and Pd (II) complexes and catalytic application in the Suzuki-Miyaura reaction. Journal of Saudi Chemical Society. 2019. Vol. 23, no. 1, pp.104-110.
https://search.emarefa.net/detail/BIM-892750
Data Type
Journal Articles
Language
English
Notes
Includes margin notes : p. 109
Record ID
BIM-892750