Synthesis of composite of ZnO spheres with polyaniline and their microwave absorption properties

Abstract EN

Three-dimensional (3D) ZnO microspheres with the composite of polyaniline (PANI) have been successfully synthesized by one-pot solvothermal and in-suit polymerization method.

The obtained microspheres were uniform having the diameter of 4 lm–7 lm.

These microspheres, inside cushion of PANI polymer, exhibit excellent microwave absorption properties.

Composite of ZnO microspheres with PANI increased the complex permeability and enhanced the dielectric loss.

Thus, the microwave absorption properties of the composite have been intensified.

Despite the fact that the composite of ZnO with PANI herein dissipate the microwaves by dielectric loss, their performance is admirable compared to most of PANI-based composites reported.

The morphological, structural and spectral properties have been investigated using scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) and the Fourier transform infrared (FT-IR).

It is found that the maximum reflection loss value of ZnO@PANI reaches 41 dB at 14 GHz with a thickness of 3.5 mm that is superior to the previously reported composite of PANI with other materials.