Synthesis and characterization of new Co(II), Ni(II), Cu(II) and Zn(II) with bis-hydrazones complexes
Other Title(s)
تحضير و تشخيص معقدات جديدة ل Co(II)، Ni(II)، Cu(II) و Zn(II) ثنائية الهيدرازون
Joint Authors
al-Dabbagh, Ahmad A.
al-Zahir, Abd al-Ghani M.
Source
Publisher
University of Mosul College of Science
Publication Date
2019-04-30
Country of Publication
Iraq
No. of Pages
8
Main Subjects
Topics
English Abstract
A number of new Co(II), Ni(II), Cu(II) and Zn(II) complexes with 2,5-hexanedione bis(4-methylbenzoyl hydrazone)(HDMBH), 2,5-hexanedione bis(2-theonyl hydrazone)(HDTH) and 2,5-hexanedione bis(2-furoyl hydrazone)(HDFH) have been reported.The bis-hydrazone ligands were synthesized by the condensation of 2,5-hexanedione with (4-methylbenzoic acid hydrazide,2-thiophene carbohydrazide or 2-furic acid carbohydrazide) in 1:2 molar ratio.
The reaction of metal(II) chlorides with the ligands in (1:1) molar ratio in ethanol in presence of triethylamine lead to the isolation of complexes having the general formula [M(L-2H)(H2O)2] where (M= Co(II), Ni(II), Cu(II) and Zn(II)) and (L-2H=doubly deprotonated ligand).
The ligands and complexes have been characterized by elemental analysis, spectral (IR,UV-Vis), magnatic and molar conductance measurements, which revealed that the ligands HDMBH, HDTH, and HDFH act as dinegtive charge tetradentate (NNOO-2) donor ligands in the metal complexes, coordinated through the two azomethine group nitrogen atoms and the two enolic oxygen atoms.
All complexes provide an octaheadral geomatry.
Data Type
Conference Papers
Record ID
BIM-894967
American Psychological Association (APA)
al-Dabbagh, Ahmad A.& al-Zahir, Abd al-Ghani M.. 2019-04-30. Synthesis and characterization of new Co(II), Ni(II), Cu(II) and Zn(II) with bis-hydrazones complexes. Growing Chemistry Science and its Application (3 : 2019 : Banghazi, Libya). . Vol. 28, no. 2 (Special issue) (2019), pp.112-119.Mosul Iraq : University of Mosul College of Science.
https://search.emarefa.net/detail/BIM-894967
Modern Language Association (MLA)
al-Dabbagh, Ahmad A.& al-Zahir, Abd al-Ghani M.. Synthesis and characterization of new Co(II), Ni(II), Cu(II) and Zn(II) with bis-hydrazones complexes. . Mosul Iraq : University of Mosul College of Science. 2019-04-30.
https://search.emarefa.net/detail/BIM-894967
American Medical Association (AMA)
al-Dabbagh, Ahmad A.& al-Zahir, Abd al-Ghani M.. Synthesis and characterization of new Co(II), Ni(II), Cu(II) and Zn(II) with bis-hydrazones complexes. . Growing Chemistry Science and its Application (3 : 2019 : Banghazi, Libya).
https://search.emarefa.net/detail/BIM-894967
