Interactions study of Co-enzyme-Q0 with aniline and pyrrole using square wave voltammetric technique

Other Title(s)

دراسة تداخلات مساعد الأنزيم Q0 مع الأنيلين و البايرول باستخدام فولتامتري الموجة المربعة

Joint Authors

Rahawi, Qasim Y.
Sulayman, Sad Allah T.
Sharif, Nada B.

Source

Rafidain Journal of Science

Publisher

University of Mosul College of Science

Publication Date

2019-04-30

Country of Publication

Iraq

No. of Pages

11

Main Subjects

Chemistry

Topics

English Abstract

The interactions of Co-enzyme Q0 with Aniline and Pyrrole were studied in aqueous phosphate buffer solution at (pH=7.0) as supporting electrolyte using square wave voltammetry, Co-enzyme Q0 gives a well-defined square wave voltammetric peak at (-0.0415) volt against the reference electrode (Ag/AgCl/3M KCl).

The binding constants (K) were calculated at different temperatures.

Vant's hoff equation is applied to calculate the thermodynamic parametrs (ΔH enthalpy changes, ΔS entropy changes and ΔG free energy changes), and then the type of interaction was estimated.

The results indicated that the interaction between Co-enzyme –Q0 and Aniline (ΔH and ΔS negative values) was probably due to Vander Waals forces or hydrogen bonding interaction, and the second interaction between Co-enzyme-Q0 with Pyrrole (ΔH and ΔS positive values) might be due to the hydrophobic interaction.

Data Type

Conference Papers

Record ID

BIM-895034

American Psychological Association (APA)

Sharif, Nada B.& Sulayman, Sad Allah T.& Rahawi, Qasim Y.. 2019-04-30. Interactions study of Co-enzyme-Q0 with aniline and pyrrole using square wave voltammetric technique. Growing Chemistry Science and its Application (3 : 2019 : Banghazi, Libya). . Vol. 28, no. 2 (Special issue) (2019), pp.193-203.Mosul Iraq : University of Mosul College of Science.
https://search.emarefa.net/detail/BIM-895034

Modern Language Association (MLA)

Sharif, Nada B.…[et al.]. Interactions study of Co-enzyme-Q0 with aniline and pyrrole using square wave voltammetric technique. . Mosul Iraq : University of Mosul College of Science. 2019-04-30.
https://search.emarefa.net/detail/BIM-895034

American Medical Association (AMA)

Sharif, Nada B.& Sulayman, Sad Allah T.& Rahawi, Qasim Y.. Interactions study of Co-enzyme-Q0 with aniline and pyrrole using square wave voltammetric technique. . Growing Chemistry Science and its Application (3 : 2019 : Banghazi, Libya).
https://search.emarefa.net/detail/BIM-895034