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Preparation, characterization and study of ethyl pyruvate aroyl hydrazone metal complexes
Other Title(s)
تحضير و تشخيص و دراسة بعض معقدات الفلزات مع هيدرازونات الارويل لبايروفات الاثيل
Joint Authors
Muhammad, Ammar H.
al-Zahir, Abd al-Ghani M.
Source
Issue
Vol. 27, Issue 3 (30 Jun. 2018), pp.103-115, 13 p.
Publisher
University of Mosul College of Science
Publication Date
2018-06-30
Country of Publication
Iraq
No. of Pages
13
Main Subjects
Topics
Abstract EN
Hydrazones derived from aroyl hydrazides and ethyl pyruvate namely; ethyl pyruvate benzoyl hydrazone (EPBH), ethyl pyruvate salicyloyl hydrazone (EPSH), ethyl pyruvate-2-furoyl hydrazone (EPFH) and ethyl pyruvate-2-thiophenoyl hydrazone (EPTH) have been synthesized and used in preparing the corresponding Mn(II), Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) complexes.
The ligands undergo deprotonation forming neutral mononuclear octahedral bis-complexes of the type [M(L-H)2] where L-H = deprotonated EPBH, EPSH, EPFH or EPTH, acting as uni-negative tridentate ligands.
The complexes isolated were characterized by elemental analyses, IR, electronic, 1H-NMR spectra, molar conductance and magnetic susceptibility measurements.
The bonding and probable structure of the complexes are discussed on the basis of the spectral and magnetic data.
The ligands, as well as some of their complexes, screened against Gram-positive and Gramnegative bacteria.
American Psychological Association (APA)
al-Zahir, Abd al-Ghani M.& Muhammad, Ammar H.. 2018. Preparation, characterization and study of ethyl pyruvate aroyl hydrazone metal complexes. Rafidain Journal of Science،Vol. 27, no. 3, pp.103-115.
https://search.emarefa.net/detail/BIM-901473
Modern Language Association (MLA)
al-Zahir, Abd al-Ghani M.& Muhammad, Ammar H.. Preparation, characterization and study of ethyl pyruvate aroyl hydrazone metal complexes. Rafidain Journal of Science Vol. 27, no. 3 (2018), pp.103-115.
https://search.emarefa.net/detail/BIM-901473
American Medical Association (AMA)
al-Zahir, Abd al-Ghani M.& Muhammad, Ammar H.. Preparation, characterization and study of ethyl pyruvate aroyl hydrazone metal complexes. Rafidain Journal of Science. 2018. Vol. 27, no. 3, pp.103-115.
https://search.emarefa.net/detail/BIM-901473
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 114-115
Record ID
BIM-901473