Preparation, characterization and biological study of new azo-oxime ligand and some of its metal complexes
Joint Authors
Awn, Isra Karim Abid
al-Khafaji, Abbas Hmud
Ali, Abd Allah M.
Source
Journal of Kufa for Chemical Science
Issue
Vol. 2, Issue 3 (31 Dec. 2017), pp.1-16, 16 p.
Publisher
University of Kufa Faculty of Education for Women Department of Chemistry
Publication Date
2017-12-31
Country of Publication
Iraq
No. of Pages
16
Main Subjects
Topics
Abstract EN
New chelate compounds, with general formula [M (HL)2(H2O)2].
when [M= Co(II), Ni(II), and Cu(II)] and [M (HL)2].(H2O)2 for Zn(II) and Cd(II), were prepared by reacting chloride salts of these metal with new azo-oxime ligand 2-Hydroxy(3-trifloromethylphenylazo)-benzaldehydeoxime (H2L), which was prepared by coupling of diazonium salt of 3-Methylanilin with Salicylaldoxime.
The new azo-oxime ligand and its chelate complexes were characterized by available techniques and the results showed that Co(II), Ni(II), and Cu(II)] chelate complexes have octahedral geometry where Zn(II) and Cd(II), have tetrahedral geometry.
The ligand and their metal complexes was tested invitro against the sensitive organisms Staphyllococcus aureus, Streptococcus mutants, Escherichia coli and Proteus mirabilis as antibacterial and Aspergillus flavus, Aspergillus terreus as fungicidal.
The activity data show that the metal complexes higher antibacterial and antifungus activity than the free ligand.
American Psychological Association (APA)
Awn, Isra Karim Abid& al-Khafaji, Abbas Hmud& Ali, Abd Allah M.. 2017. Preparation, characterization and biological study of new azo-oxime ligand and some of its metal complexes. Journal of Kufa for Chemical Science،Vol. 2, no. 3, pp.1-16.
https://search.emarefa.net/detail/BIM-903483
Modern Language Association (MLA)
Awn, Isra Karim Abid…[et al.]. Preparation, characterization and biological study of new azo-oxime ligand and some of its metal complexes. Journal of Kufa for Chemical Science Vol. 2, no. 3 (Dec. 2017), pp.1-16.
https://search.emarefa.net/detail/BIM-903483
American Medical Association (AMA)
Awn, Isra Karim Abid& al-Khafaji, Abbas Hmud& Ali, Abd Allah M.. Preparation, characterization and biological study of new azo-oxime ligand and some of its metal complexes. Journal of Kufa for Chemical Science. 2017. Vol. 2, no. 3, pp.1-16.
https://search.emarefa.net/detail/BIM-903483
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 15-16
Record ID
BIM-903483