Joined liquid ion exchange with cloud point extraction methods for separation and determination of Cr (VI), Mn (VII)
Author
Source
Journal of Kufa for Chemical Science
Issue
Vol. 2, Issue 1 (30 Jun. 2016), pp.1-14, 14 p.
Publisher
University of Kufa Faculty of Education for Women Department of Chemistry
Publication Date
2016-06-30
Country of Publication
Iraq
No. of Pages
14
Main Subjects
Abstract EN
Sensitive and selective extraction method used for separation, preconcentration and spectrophotometric determination of Cr(VI) as Cr2O7= and Mn(VII) as MnO4- from HCl media by used Janus green B after formation ion pair association complex, studies the optimum condition for extraction demonstrated 0.1M and 0.05M of HCl suitable for extraction efficiency of Cr(VI) and Mn(VII) respectively , in presence 50µg Mn(VII) or 20µg of Cr(VI).
with 0.8mL 1% TritonX-100 for extraction ion pair association of Cr(VI) as well as 0.5mL for Mn(VII) and 95°C suitable for formation CPL and extraction ion pair complex for both metal ions ,with 15 min.
of heating time for both metal ions.
Then study effect of interferences and electrolyte presence.
This method applied for spectrophotometric determination of Cr(VI) and Mn(VII) in different samples.
The wave length for maximum absorbance of ion pair complex extracted was λmax=560 nm for Mn(VII) and 603nm for Cr(VI) complexes
American Psychological Association (APA)
Jawad, Shawkat Kazim. 2016. Joined liquid ion exchange with cloud point extraction methods for separation and determination of Cr (VI), Mn (VII). Journal of Kufa for Chemical Science،Vol. 2, no. 1, pp.1-14.
https://search.emarefa.net/detail/BIM-904657
Modern Language Association (MLA)
Jawad, Shawkat Kazim. Joined liquid ion exchange with cloud point extraction methods for separation and determination of Cr (VI), Mn (VII). Journal of Kufa for Chemical Science Vol. 2, no. 1 (Jun. 2016), pp.1-14.
https://search.emarefa.net/detail/BIM-904657
American Medical Association (AMA)
Jawad, Shawkat Kazim. Joined liquid ion exchange with cloud point extraction methods for separation and determination of Cr (VI), Mn (VII). Journal of Kufa for Chemical Science. 2016. Vol. 2, no. 1, pp.1-14.
https://search.emarefa.net/detail/BIM-904657
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 14
Record ID
BIM-904657