Synthesis and characterization of some METAL complexes with some furanose rings and study their biological activity
Joint Authors
Nasir, Ahmad Wahid
Abbas, Nada Muhammad
Source
al-Kufa University Journal for Biology
Issue
Vol. 5, Issue 2 (31 Dec. 2013)10 p.
Publisher
University of Kufa Faculty of Science Department of live Sciences
Publication Date
2013-12-31
Country of Publication
Iraq
No. of Pages
10
Main Subjects
Abstract EN
1,2:5,6-Di-O-isopropylidene (2) as starting material have been synthesized by the reaction of D-glucose with dry acetone in presence of Zncl2/H3Po3.3-ullos derived (3) was prepared by oxidation of (2) with DMSO/Ac2O.
Hydrolysis of (2) and (3) by 60% Ac2O gave the corresponding derivateivies 1,2-O- isopropytidene –α – D -glucofuranose (L1) and 1,2-isoproplyene-α-D-ribohexafuranose-3-ulos(LΠ).
Coordination chemistry of L1and LΠ with Co(Π), Cu(Π), Ni(Π), Pd(Π) and Pt(ІV) ions were studied.
The two ligands were characterized depending upon CHN analyses, Ή NMR and FTIR.
Structure of metal complexes were proposed depending on atomic absorption, CHN, Thermal analyses (TG & DTG), FTIR spectra, uv-vis and chloride contents, magnetic moments (meft) as well as conductivity measurements.
From the spectral measurements, monomer structures for the complexes were proposed.
The newly metal complexes were subjected to in vitro testing agains pathogenic microorganisms.
American Psychological Association (APA)
Abbas, Nada Muhammad& Nasir, Ahmad Wahid. 2013. Synthesis and characterization of some METAL complexes with some furanose rings and study their biological activity. al-Kufa University Journal for Biology،Vol. 5, no. 2.
https://search.emarefa.net/detail/BIM-939718
Modern Language Association (MLA)
Abbas, Nada Muhammad& Nasir, Ahmad Wahid. Synthesis and characterization of some METAL complexes with some furanose rings and study their biological activity. al-Kufa University Journal for Biology Vol. 5, no. 2 (2013).
https://search.emarefa.net/detail/BIM-939718
American Medical Association (AMA)
Abbas, Nada Muhammad& Nasir, Ahmad Wahid. Synthesis and characterization of some METAL complexes with some furanose rings and study their biological activity. al-Kufa University Journal for Biology. 2013. Vol. 5, no. 2.
https://search.emarefa.net/detail/BIM-939718
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-939718