Preparation and characterization of some transition metal complexes with two mixed ligands macrocyclic and ligands PPh3
Other Title(s)
تحضير و تشخيص بعض معقدات العناصر الانتقالية مع مزيج من ليكندين حلقي كبير و ليكند ثلاثي فنيل فوسفين
Joint Authors
Fakhri, Falah Muhammad
Dawud, Sad Khidr
Source
Issue
Vol. 28, Issue 4 (31 Dec. 2019), pp.29-37, 9 p.
Publisher
University of Mosul College of Science
Publication Date
2019-12-31
Country of Publication
Iraq
No. of Pages
9
Main Subjects
Abstract EN
A new ligand (3,4,6,14,15,17,23,24-octaazatricyclo [17.3.1.18,12] tetracosa-1(23),8(24),9,11, 19, 21- hexaene - 2,5,7,13,16,18 – hexaone), (CHT) was been prepared from the reaction of pyridine-2,6-dicarboxylic acid with semicarbazide using microwave irradiation in solid state.
The ligand is reacted with some transition metal(II) ions to form complexes of the type [Co(CHT)]Cl2, [Fe(CHT) Cl]Cl and [M(CHT)Cl2] where (M=Mn(II), Ni(II), Cu(II) and Zn(II)).
Complexes of the type [Ni(CHT)(PPh3)]Cl2 and [M(CHT)(PPh3)Cl]Cl where (M=Mn(II), Fe(II), Co(II), Cu(II) and Zn(II)), were prepared by the reaction of the above complexes with triphenylphosphine(PPh3) in a 1:1 molar ratio.
All the complexes were characterized by (C,H,N) analysis, metal content analysis, molar conductance, magnetic moment measurements, electronic and IR spectroscopy, as well as the ligand was characterized by 1H ,13C -NMR.
The electronic spectra and magnetic measurements indicate that the complexes have octahedral environment around the metal ions, except cobalt complex have square planer geometry.
American Psychological Association (APA)
Fakhri, Falah Muhammad& Dawud, Sad Khidr. 2019. Preparation and characterization of some transition metal complexes with two mixed ligands macrocyclic and ligands PPh3. Rafidain Journal of Science،Vol. 28, no. 4, pp.29-37.
https://search.emarefa.net/detail/BIM-950115
Modern Language Association (MLA)
Fakhri, Falah Muhammad& Dawud, Sad Khidr. Preparation and characterization of some transition metal complexes with two mixed ligands macrocyclic and ligands PPh3. Rafidain Journal of Science Vol. 28, no. 4 (2019), pp.29-37.
https://search.emarefa.net/detail/BIM-950115
American Medical Association (AMA)
Fakhri, Falah Muhammad& Dawud, Sad Khidr. Preparation and characterization of some transition metal complexes with two mixed ligands macrocyclic and ligands PPh3. Rafidain Journal of Science. 2019. Vol. 28, no. 4, pp.29-37.
https://search.emarefa.net/detail/BIM-950115
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 36-37
Record ID
BIM-950115