Synthesis of six and seven-membered heterocyclic molecules containing an adamantyl fragment and an X-ray crystal structure of (E)-N-(adamantan-1-yl)-1-(3-nitrophenyl) methanimine
Other Title(s)
تحضير جزيئات سداسية و سباعية حلقية غير متجانسة حاوية على جزء الادامنتيل و الأشعة السينية للتركيب البلوري لمركب N-(E)-(ادامنتان-1-يل)-1-(3-نايتروفينيل) ميثانيمين
Joint Authors
Ismail, Ali Sami
Salih, Ahmad Dari
Shukr, Ahmad Hamad
Source
Issue
Vol. 17, Issue 1 (sup) (31 Mar. 2020), pp.272-286, 15 p.
Publisher
University of Baghdad College of Science for Women
Publication Date
2020-03-31
Country of Publication
Iraq
No. of Pages
15
Main Subjects
Abstract EN
Our work included a synthesis of three new imine derivatives—1,3-thiazinan-4-one, 1,3-oxazinan-6-one and 1,3-oxazepin-4,7-dione—which contained an adamantyl fragment.
These were produced via the condensation of the Schiff`s base (E)-N-(adamantan-1-yl)-1-(3-aryl)methanimine with 3-mercaptopropanoic acid; 3-chloropropanoic acid; and maleic, citraconic anhydride, respectively.
These new imines were prepared via the condensation of adamantan-1-ylamine and 3-nitro-, 3-bromobenzaldehyde in n-BuOH.
We obtained a good yield of products.
FTIR, 1H NMR spectroscopy and C.H.N.S analysis were used to diagnostic the products.
The molecular structure of (E)-N-(adamantan-1-yl)-1-(3-nitrophenyl)methanimine was confirmed by X-ray crystallography analysis.
American Psychological Association (APA)
Shukr, Ahmad Hamad& Ismail, Ali Sami& Salih, Ahmad Dari. 2020. Synthesis of six and seven-membered heterocyclic molecules containing an adamantyl fragment and an X-ray crystal structure of (E)-N-(adamantan-1-yl)-1-(3-nitrophenyl) methanimine. Baghdad Science Journal،Vol. 17, no. 1 (sup), pp.272-286.
https://search.emarefa.net/detail/BIM-970031
Modern Language Association (MLA)
Shukr, Ahmad Hamad…[et al.]. Synthesis of six and seven-membered heterocyclic molecules containing an adamantyl fragment and an X-ray crystal structure of (E)-N-(adamantan-1-yl)-1-(3-nitrophenyl) methanimine. Baghdad Science Journal Vol. 17, no. 1 (Supplement) (Mar. 2020), pp.272-286.
https://search.emarefa.net/detail/BIM-970031
American Medical Association (AMA)
Shukr, Ahmad Hamad& Ismail, Ali Sami& Salih, Ahmad Dari. Synthesis of six and seven-membered heterocyclic molecules containing an adamantyl fragment and an X-ray crystal structure of (E)-N-(adamantan-1-yl)-1-(3-nitrophenyl) methanimine. Baghdad Science Journal. 2020. Vol. 17, no. 1 (sup), pp.272-286.
https://search.emarefa.net/detail/BIM-970031
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references : p. 285-286
Record ID
BIM-970031
