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DNA Binding Test, X-Ray Crystal Structure, Spectral Studies, TG-DTA, and Electrochemistry of [CoX2(dmdphphen)] (Dmdphphen Is 2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline, X = Cl, and NCS) Complexes
المؤلفون المشاركون
Darwish, Hany W.
Al-Noaimi, Mousa
Suleiman, Mohammed
Bakheit, Ahmed H.
Abdoh, Muneer
Saadeddin, Iyad
Shivalingegowda, Naveen
Lokanath, Neartur Krishnappagowda
Bsharat, Odey
Barakat, Assem
Warad, Ismail
المصدر
Bioinorganic Chemistry and Applications
العدد
المجلد 2014، العدد 2014 (31 ديسمبر/كانون الأول 2014)، ص ص. 1-7، 7ص.
الناشر
Hindawi Publishing Corporation
تاريخ النشر
2014-12-29
دولة النشر
مصر
عدد الصفحات
7
التخصصات الرئيسية
الملخص EN
Two new neutral mixed-ligand cobalt(II) complexes, [CoCl2(dmdphphen)] 1 and [Co(NCS)2(dmdphphen)] 2, where dmdphphen is 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline, were synthesized and characterized by an elemental analysis, UV-Vis, IR, TG/DTA, cyclic voltammetry CV, and single X-ray diffraction.
Complex 2 crystallized as monoclinic with a space group P21/c.
Co(II) ions are located in a distorted tetrahedral environment.
TG/DTA result shows that these complexes are very stable and decomposed through one-step reaction.
The two complexes exhibit a quasireversible one-electron response at −550 and 580 mV versus Cp2Fe/Cp2Fe+, which has been assigned to Co(I)/Co(II) and Co(II)/Co(III) couples.
Absorption spectral studies reveal that such complexes exhibit hypochromicity during their interaction with CT-DNA.
نمط استشهاد جمعية علماء النفس الأمريكية (APA)
Al-Noaimi, Mousa& Suleiman, Mohammed& Darwish, Hany W.& Bakheit, Ahmed H.& Abdoh, Muneer& Saadeddin, Iyad…[et al.]. 2014. DNA Binding Test, X-Ray Crystal Structure, Spectral Studies, TG-DTA, and Electrochemistry of [CoX2(dmdphphen)] (Dmdphphen Is 2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline, X = Cl, and NCS) Complexes. Bioinorganic Chemistry and Applications،Vol. 2014, no. 2014, pp.1-7.
https://search.emarefa.net/detail/BIM-1034374
نمط استشهاد الجمعية الأمريكية للغات الحديثة (MLA)
Al-Noaimi, Mousa…[et al.]. DNA Binding Test, X-Ray Crystal Structure, Spectral Studies, TG-DTA, and Electrochemistry of [CoX2(dmdphphen)] (Dmdphphen Is 2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline, X = Cl, and NCS) Complexes. Bioinorganic Chemistry and Applications No. 2014 (2014), pp.1-7.
https://search.emarefa.net/detail/BIM-1034374
نمط استشهاد الجمعية الطبية الأمريكية (AMA)
Al-Noaimi, Mousa& Suleiman, Mohammed& Darwish, Hany W.& Bakheit, Ahmed H.& Abdoh, Muneer& Saadeddin, Iyad…[et al.]. DNA Binding Test, X-Ray Crystal Structure, Spectral Studies, TG-DTA, and Electrochemistry of [CoX2(dmdphphen)] (Dmdphphen Is 2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline, X = Cl, and NCS) Complexes. Bioinorganic Chemistry and Applications. 2014. Vol. 2014, no. 2014, pp.1-7.
https://search.emarefa.net/detail/BIM-1034374
نوع البيانات
مقالات
لغة النص
الإنجليزية
الملاحظات
Includes bibliographical references
رقم السجل
BIM-1034374
قاعدة معامل التأثير والاستشهادات المرجعية العربي "ارسيف Arcif"
أضخم قاعدة بيانات عربية للاستشهادات المرجعية للمجلات العلمية المحكمة الصادرة في العالم العربي
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