DNA Binding Test, X-Ray Crystal Structure, Spectral Studies, TG-DTA, and Electrochemistry of [CoX2(dmdphphen)] (Dmdphphen Is 2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline, X = Cl, and NCS) Complexes
Joint Authors
Darwish, Hany W.
Al-Noaimi, Mousa
Suleiman, Mohammed
Bakheit, Ahmed H.
Abdoh, Muneer
Saadeddin, Iyad
Shivalingegowda, Naveen
Lokanath, Neartur Krishnappagowda
Bsharat, Odey
Barakat, Assem
Warad, Ismail
Source
Bioinorganic Chemistry and Applications
Issue
Vol. 2014, Issue 2014 (31 Dec. 2014), pp.1-7, 7 p.
Publisher
Hindawi Publishing Corporation
Publication Date
2014-12-29
Country of Publication
Egypt
No. of Pages
7
Main Subjects
Abstract EN
Two new neutral mixed-ligand cobalt(II) complexes, [CoCl2(dmdphphen)] 1 and [Co(NCS)2(dmdphphen)] 2, where dmdphphen is 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline, were synthesized and characterized by an elemental analysis, UV-Vis, IR, TG/DTA, cyclic voltammetry CV, and single X-ray diffraction.
Complex 2 crystallized as monoclinic with a space group P21/c.
Co(II) ions are located in a distorted tetrahedral environment.
TG/DTA result shows that these complexes are very stable and decomposed through one-step reaction.
The two complexes exhibit a quasireversible one-electron response at −550 and 580 mV versus Cp2Fe/Cp2Fe+, which has been assigned to Co(I)/Co(II) and Co(II)/Co(III) couples.
Absorption spectral studies reveal that such complexes exhibit hypochromicity during their interaction with CT-DNA.
American Psychological Association (APA)
Al-Noaimi, Mousa& Suleiman, Mohammed& Darwish, Hany W.& Bakheit, Ahmed H.& Abdoh, Muneer& Saadeddin, Iyad…[et al.]. 2014. DNA Binding Test, X-Ray Crystal Structure, Spectral Studies, TG-DTA, and Electrochemistry of [CoX2(dmdphphen)] (Dmdphphen Is 2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline, X = Cl, and NCS) Complexes. Bioinorganic Chemistry and Applications،Vol. 2014, no. 2014, pp.1-7.
https://search.emarefa.net/detail/BIM-1034374
Modern Language Association (MLA)
Al-Noaimi, Mousa…[et al.]. DNA Binding Test, X-Ray Crystal Structure, Spectral Studies, TG-DTA, and Electrochemistry of [CoX2(dmdphphen)] (Dmdphphen Is 2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline, X = Cl, and NCS) Complexes. Bioinorganic Chemistry and Applications No. 2014 (2014), pp.1-7.
https://search.emarefa.net/detail/BIM-1034374
American Medical Association (AMA)
Al-Noaimi, Mousa& Suleiman, Mohammed& Darwish, Hany W.& Bakheit, Ahmed H.& Abdoh, Muneer& Saadeddin, Iyad…[et al.]. DNA Binding Test, X-Ray Crystal Structure, Spectral Studies, TG-DTA, and Electrochemistry of [CoX2(dmdphphen)] (Dmdphphen Is 2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline, X = Cl, and NCS) Complexes. Bioinorganic Chemistry and Applications. 2014. Vol. 2014, no. 2014, pp.1-7.
https://search.emarefa.net/detail/BIM-1034374
Data Type
Journal Articles
Language
English
Notes
Includes bibliographical references
Record ID
BIM-1034374