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Synthesis and Characterization of Bioactive Acylpyrazolone Sulfanilamides and Their Transition Metal Complexes: Single Crystal Structure of 4-Benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one Sulfanilamide
المؤلفون المشاركون
Idemudia, Omoruyi Gold
Sadimenko, Alexander P.
Hosten, Eric C.
Afolayan, Anthony Jide
المصدر
Bioinorganic Chemistry and Applications
العدد
المجلد 2015، العدد 2015 (31 ديسمبر/كانون الأول 2015)، ص ص. 1-14، 14ص.
الناشر
Hindawi Publishing Corporation
تاريخ النشر
2015-05-27
دولة النشر
مصر
عدد الصفحات
14
التخصصات الرئيسية
الملخص EN
Two Schiff base ligands Ampp-Sn 1 and Bmpp-Sn 2, afforded by a condensation reaction between sulfanilamide and the respective acylpyrazolone carbonyl precursors, their Mn(II), Co(II), Ni(II), and Cu(II) complexes prepared by the reaction of ligands and corresponding metal salts in aqueous solutions, were synthesized and then characterized by both analytical and spectroscopic methods, in a view to developing new improved bioactive materials with novel properties.
On the basis of elemental analysis, spectroscopic and TGA results, transition metal complexes, with octahedral geometry having two molecules of the bidentate keto-imine ligand each, have been proposed.
The single crystal structure of Bmpp-Sn according to X-ray crystallography showed a keto-imine tautomer type of Schiff base, having three intramolecular bonds, one short N2 ⋯ H2 ⋯ O3 hydrogen bond of 1.90 Å and two long C13 ⋯ H13 ⋯ O2 and C32 ⋯ H32 ⋯ O3 hydrogen bonds of 2.48 Å.
A moderate to low biological activities have been exhibited by synthesized compounds when compared with standard antimicrobial agents on screening the synthesized compounds against Staphylococcus aureus, Bacillus pumilus, Proteus vulgaris, and Aeromonas hydrophila for antibacterial activity and against free radical 1, 1-diphenyl-2-picryl-hydrazyl (DPPH) for antioxidant activity.
نمط استشهاد جمعية علماء النفس الأمريكية (APA)
Idemudia, Omoruyi Gold& Sadimenko, Alexander P.& Afolayan, Anthony Jide& Hosten, Eric C.. 2015. Synthesis and Characterization of Bioactive Acylpyrazolone Sulfanilamides and Their Transition Metal Complexes: Single Crystal Structure of 4-Benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one Sulfanilamide. Bioinorganic Chemistry and Applications،Vol. 2015, no. 2015, pp.1-14.
https://search.emarefa.net/detail/BIM-1054052
نمط استشهاد الجمعية الأمريكية للغات الحديثة (MLA)
Idemudia, Omoruyi Gold…[et al.]. Synthesis and Characterization of Bioactive Acylpyrazolone Sulfanilamides and Their Transition Metal Complexes: Single Crystal Structure of 4-Benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one Sulfanilamide. Bioinorganic Chemistry and Applications No. 2015 (2015), pp.1-14.
https://search.emarefa.net/detail/BIM-1054052
نمط استشهاد الجمعية الطبية الأمريكية (AMA)
Idemudia, Omoruyi Gold& Sadimenko, Alexander P.& Afolayan, Anthony Jide& Hosten, Eric C.. Synthesis and Characterization of Bioactive Acylpyrazolone Sulfanilamides and Their Transition Metal Complexes: Single Crystal Structure of 4-Benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one Sulfanilamide. Bioinorganic Chemistry and Applications. 2015. Vol. 2015, no. 2015, pp.1-14.
https://search.emarefa.net/detail/BIM-1054052
نوع البيانات
مقالات
لغة النص
الإنجليزية
الملاحظات
Includes bibliographical references
رقم السجل
BIM-1054052
قاعدة معامل التأثير والاستشهادات المرجعية العربي "ارسيف Arcif"
أضخم قاعدة بيانات عربية للاستشهادات المرجعية للمجلات العلمية المحكمة الصادرة في العالم العربي
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